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Miller Indices
Popularized by William H. Miller, Miller indices is a notation
system in crystallography for
1. Planes (hkl) or family of planes {hkl}
2. Directions [hkl] or family of directions <hkl>
in crystal (Bravais) lattices. In particular, a family of lattice
planes is determined by three integers h, k, and , called
the Miller indices.
. These h, k and are basically rounded integers
determining the magnitudes in x, y and z coordinates.
. The number of indices will match with the dimension
of the lattice or the crystal.
E.g. in 1D there will be 1 index and 2D there will be two
indices etc.
ME202 Material Science
Miller Indices
In Materials Science it is important to have a
notation system for atomic planes since these
planes influence
Optical properties
Reactivity
Surface tension
Dislocations
, , and
c1 = pa, c2 = qb and c3 = rc
If unit cell is cubical then
a = b = c=1 then
c1 = p, c2 = q and c3 = r
The ratio of the reciprocals is taken as
These reciprocals are finally converted into whole
numbers by multiplying by their LCM.
Summary
1. Plane intercepts on the x, y and z-axes
are identified.
2. Intercepts are measured in terms of
dimensions of the unit cell.
3. Reciprocals of the fractional intercepts is
taken and then rounded.
,
p = Intercept of the plane on the x axis
q = Intercept of the plane on the y axis
r = Intercept of the plane on the z axis
ME202 Material Science
Intercepts 1
Plane (100)
Intercepts 1 1
Plane (110)
Intercepts 1 1 1
Plane (111)
(Octahedral plane)
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Problem
Q. For cubical unit cell,
determine the Miller indices of
plane ABC. Origin O and
coordinate axes x, y and z are
shown in the unit cell in which
OP = OQ = OR = a. The plane
intercepts the x, y and z axes
in such a way that
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Directions
Two dimensional lattice array
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Directions
Three dimensional lattice array
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Family of Directions
Its a set of directions related by symmetry operations
of the lattice.
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NaCl Problem
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