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Chapter 4
2
Concept of a Material Balance
A material
balance can be considered as an accounting for material
in a process
DATE ACTIVITY DEPOSIT WITHDRAWAL BALANCE
3/1 Beginning Balance 100.00
If
If
140 Then
kPa
10C 43
C
4
Material Balance can refer to a balance
on a system for the:
- Total mass
- Total moles
- Mass of a chemical compound
- Mass of an atomic species
- Moles of a chemical compound
- Moles of an atomic species
- Volume (possibly)
5
input: enters through system boundaries
output: leaves through system boundaries
generation: produced within the system
(reaction)
consumption: consumed within the system
(reaction)
accumulation: buildup within the system 6
Two types of balances may be written for
any system;
differential balances and
integral balances
90
100
kg/min
kg/min100
100
kg/min 1000
kg/min 1000
kg
kg
Steady-State Unsteady-State
Process/System: Process/System:
Rate of water addition = rate Water accumulates at a rate of 10
of water usage, water level in kg/min
tank remain constant Thus, water level in tank depends
1. All condition inside the process on the amount of time, e.g. 1 min
remain unchanged (P, T, mass, additional 10 kg, 10 minutes?
flow rate, etc.) Amount of water changes with time
2. Condition of the flowing streams Other conditions such as P, T, flow
remain constant with time rates changes with time also 9
Material Balance
Equation
Suppose methane, is a component of both
input and output of a process
(1
)
For steady state condition: 100 kg/min 500 100 kg/min
Nothing is changing with time
Accumulation = 0 H2O kg H2O
H2O
(2
)
For unsteady-state condition:
Not all of the conditions in the process remain constant with time
Changing with time
Accumulation over time can be calculated by
(3
)11
Material Balance for Single Components
12
Material Balance for Multiple Components
13
Material Balance for Chemical Reactions
Reactor
200 L/min
1.0 molar
NaCl
14
Rules of Material Balance
If the balancedSimplification
quantity is Total Mass,
set generation = 0 and consumption = 0
20
Example 4.2-2: Continuous
Benzene/Toluene distillation
continuous process
steady-state operation
no reactions occurring
input = output
21
input = output
Benzene balance
500 kg B/h = 450 kg B/h + m2
m2 = 50 kg B/h
Toluene balance
500 kg T/h = m1 + 475 kg T/h
m1 = 25 kg T/h
Total mass balance
1000 = 450 + m1 + m2 + 475 (all with units of
kg/h)
1000 kg/h = 1000 kg/h 22
REVISION PREVIOUS CHAPTER
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REVISION PREVIOUS CHAPTER
24
REVISION PREVIOUS CHAPTER
25
REVISION PREVIOUS CHAPTER
26
Integral Balances on Batch Processes
27
Example 4.2-3
Two methanol water mixtures are
contained in separate flasks. The first
mixture contains 40.0 wt% methanol
and the second contains 70.0 wt%
methanol. If 200 g of the first mixture
is combined with 150g of the second,
what are the mass and composition of
the product?
28
If the flasks are mixed, what is the mass
and concentration of the resulting product?
no reactions, generation = consumption = 0
input = output
29
Total Mass Balance
200 g + 150 g = m = 350 g
Methanol balance
0.400gCH3OH 0.700gCH3OH x gCH3OH
200g 150g m g
g g g
gCH3OH
x 0.529
g
Water balance
200(0.6) + 150(0.3) = 350(1-0.529)
165 g H2O = 165 g H2O
30
Example
31
Flowcharts
Normally, a Process Flow Sheets (PFS) or Process Flow Diagram
(PFD) comprises:
All major equipment/units
Lines entering or leaving the process/unit and/or lines
connecting 2 or more process equipment/units ( these are called
streams)
Flow rate of each stream
Composition of each stream
Operating conditions of each stream and/or unit/equipment
Qin
(e.g. T,P)
Energy/heat needed to be added to and /or removed from any
100
part of the 0.21
process
kg/h kg A/kg
or the entire process
m kg/h m kg/h
T=250
0.79 kg B/kg
0.3 kg A/kg
o
C 0.1 kg A/kg
100 0.4 kg B/kg P=5 0.3 kg B/kg
kg/h
1 kg C/kg 0.3 kg C/kg atm 0.3 kg C/kg
T=25oC, P=1atm 0.4 kg D/kg
32
Examples of PFS
or PFD
Example:
38
Convert all stream quantities to one basis
Only express quantities in mol or mass
If a volumetric flow rate of a stream is given,
convert to mass or molar flow rate since
balances are not normally written in volumetric
quantities
Use consistent notations for the labelling:
39
Example : 2 Unit Distillation Columns
40
Example : 2 Unit Distillation Columns
41
Example : 2 Unit Distillation Columns
42
Example : 2 Unit Distillation Columns
43
Example : 2 Unit Distillation Columns
44
Example : 2 Unit Distillation Columns
45
Flowchart Scaling
E.g. A kilogram of Benzene is mixed with a
kilogram of Toluene. The output of this
process is 2 kilograms of a mixture that is
50% mass of each component.
48
A 60/40 mixture (molar)
of A and B is separated
batch wise into 2 fractions.
Scale the flowchart to a
continuous 1250 lbmol/hr feed rate.
50
Basis of Calculation
Since a flowchart can always be scaled,
material balance calculations can be
performed on the basis of any
convenient set of stream amounts or
flow rates and the results can subsequently
be scaled to any desired extent.
A basis of calculation is an amount or
flow (mass or molar) of one stream or
component in a process.
The first step in balancing a process is to
chose a basis of calculation; all unknown
quantities are then determined to be
consistent with this basis. 51
If a stream amount or flow is given in a
problem statement, it is usually the most
convenient basis to use.
1.0 kg x kg C6H6/kg
C7H8/min (1-x) kg
C7H8/kg
2 unknowns:
3 balanced equation, independent or
dependent?:
Total mass balance: 1
unknown
Benzene mass 2
balance: unknown
s
Toluene mass
2
balance:
unknown
s 54
Degree of Freedom
Analysis (DoF)
DoF procedure to determine enough information to
solve a given Material & Energy balance
1. Draw and label flow chart
2. Count the unknown variables on the flow chart,
nunknowns
3. Count the independent equations relating them,
nindep. eqns.
3. Process Specification
Specification of how several process variables are related
E.g. Acetone fed is m1 in condenser, 40% appears in a
condensate stream
m2=0.4m1
57
Sources of Equations Relating Unknown Process
Variables
4. Physical Properties and Laws (Chapter 5 & 6)
Two unknown variables may be the mass and volume, where
the SG is given in tables or an equation of state
E.g. Saturation or equilibrium conditions for the stream are
given which may provide needed relations
5. Physical Constraints
E.g. Total mole/mass fraction is 1.
If stream contains components of A, B and C, then the
fractions are xA, xB dan (1-xA-xB)
58
A General Strategy for Solving
1. Understand the problem.
Material Balance
Decide the process is involves a steady state or unsteady state,
reactive or non-reactive
State your assumptions
3. Draw the block flow diagram describing the problem and fill in all
the variables including assumed and unknowns
Should include either
. Total mass or mass flow rate and mass fractions of ALL
stream components, or
. Total moles or molar flow rates and mole fractions of ALL
stream components, or 59
A continuous mixer mixes NaOH with H2O to produce an aqueous
solution of NaOH. Determine the composition and flow rate of the
product if the flow rate of NaOH is 1000 kg/hr and the ratio of the
flow rate of the H2O to the product solution is 0.9.
3
kg/h
x kg
NaOH/kg
(1-x) kg
0 H2O/kg
60
4. Express what the problem statement asks you to determine in
terms of the labeled variables
Help to identify number of unknown variables
6
DOF analysis
Number of unknowns: 2 (,
1000 kg H2O kg/h x)
Mixer
NaOH/h Number of equations to
relate: 2
i) total balance
kg/h ii) NaOH balance
iii) H2O balance
x kg ndf = nunknowns - nindep eqns
NaOH/kg
(1-x) kg = 2-2 = 0
H2O/kg 62
Problem is solvable
7. If ndf=0, then write the equations in efficient order
Start with equation with least unknown and then pairs of
simultaneous equations containing 2 unknown variables
DO NOT attempt to calculate anything ye
7
Total Mass
1000 kg H2O kg/h Balance
Mixer
NaOH/h
NaOH Component
kg/h Balance
x kg
NaOH/kg
(1-x) kg
H2O/kg 63
8. Solve the equations and calculate the quantities requested in the
problem
8
64
QUIZ: Mixing of
Methanol-
Water Mixtures
65
Example
QUIZ: Mixing 1 Steady state Mixtures
of Methanol-Water
66
ASSIGNMENT 1
Question 1
Question 2
67
HOMEWORK
Question 1
Question 2
Question 3
Question 4