CHEMICAL ENGINEERING

MATHEMATICS II
(3 SKS)

Andri Cahyo Kumoro, ST, MT, PhD

Dr. Widayat, ST ,MT

WEEK II
 ALL CHEMICAL ENGINEERING
PROBLEM SOLVING STAGES WILL
BE ROOTED FROM
CHEMICAL ENGINEERING
TOOLS
WHAT ARE THEY?

MASS BALANCE ECONOMI Are not

discussed in
ENERGY BALANCE C Chem. Eng.
Math. II
MOMENTUM HUMANIT
BALANCE Y
RATE PROCESSES
EQUILIBRIUM
 CHEMICAL ENGINEERING TOOLS:
ENERGY BALANCE
RULE to be applied: Energy
Conservation
Law
For Non-Reacting Systems
Rate of Input Rate of Output (Rate of
addition or Rate of Loss) = Rate of
Accumulation
For Reacting systems
Rate of Input Rate of Output Rate of
Reaction (Rate of addition or Rate of
Loss) = Rate of Accumulation
Note:
Energy is presented in the form of energy flow
(energy/time), either in KJ/hr, J/min, Cal/s, etc.
Accumulation is the enthalpy remains inside the
system at any time
Rate of input and Rate of Output are the
CHEMICAL ENGINEERING TOOLS:
ENERGY BALANCE
The energy calculated in chemical
engineering application are mostly in the
form of heat or enthalpy
There are two heats in general
engineering calculations. What are they?
Other heats include heat of reaction, heat
of dissolution etc.

Accumulation is the enthalpy remains inside

the system at any time or can be said as the
change of sensible heat of the material
inside the system
CHEMICAL ENGINEERING TOOLS:
ENERGY BALANCE
Sensible heat (Qs) : m. Cp. T
V. . Cp. (T-Tref)
however T ref is
usually taken as 0oC
Latent Heat (QL): m. L where L
usually in Cal/g or J/g
V. .
Heat of reaction, heatL of dissolution etc
(QR). Where HR usually available in
Cal/mol
Q = (-rA). H
R R
= the amount of reacted material
HR
therefore for a first order reaction it can
What is this system called as?

No-reacting
system
Steam is used
as heats
V
source
Fs (L/min)
T
s (g/L)
L (Cal/g)
condensate
 Reacting system
A B
An endothermic reaction of
A to form B under non-
isothermic mode according
to first order reaction
(mol A/L/min)

Heat of reaction is HR
(Cal/mol)
V Steam is used as heats
source Fs (L/min), s
CA (g/L), sL (Cal/g)
condensate
T
 To
F1
Cp

No-reacting
system

V F1

T CP Cp T

Cooling water
is used as heat
removal FCW
TCWout TCWin
(L/min), CW
 CAo CAo
F1 F1

To To

V CA
V CA
F2

CA CA

T2

CASE III? CASE I?

V CA
F2

CA CA
T2

CASE II?
 Reacting
system
Cao A B
F1
To An exothermic reaction
Cp of A to form B at a non-
isothermic mode reactor
according to first order
reaction
(mol A/L/min)
Heat of reaction is
HR (Cal/mol)
V CA
F1 Cp
T

CA CB

Cooling water T
is used as heat
removal FCW
TCWout TCWin
(L/min), CW
 CAo F2 CBo
F1
To Reacting system
To
A+B C+
D B at a
Reaction of A to form
constant temperature
according to second order
reaction
V CA
(mol A/L/min)
F
T
CA CC

CB CD
Electric heater
is used to T
supply energy
at W watt
 CHEMICAL ENGINEERING TOOLS:
RATE PROCESSES

MASS transfer rate

ENERGY Transfer
rate

MOMENTUM
Transfer rate
Chemical reaction
rate
 CHEMICAL ENGINEERING TOOLS:
ENERGY Transfer rate

onductive Transfer Rate

onvective Transfer Rate

qh

Radiative Transfer Rate

qR
 CHEMICAL ENGINEERING TOOLS:
EQUILIBRIUM

MASS transfer rate

May be achieved
ENERGY Transfer when the transfer
rates toward the two
rate or more directions
are balance (equal)
MOMENTUM
Chemicalrate
Transfer reaction
rate
CHEMICAL ENGINEERING TOOLS:
EQUILIBRIUM

vapour

liquid
CHEMICAL ENGINEERING TOOLS:
EQUILIBRIUM

vapour

liquid
CHEMICAL ENGINEERING TOOLS:
EQUILIBRIUM

liquid

solid
CHEMICAL ENGINEERING TOOLS:
EQUILIBRIUM
k1
Chemical reaction k2
rate
 CHEMICAL ENGINEERING
MATHEMATICS II (END OF THIS
SESSION)