A

PRESENTATION ON VOCATIONAL
TRAINING
ON
IOCL, MATHURA
JAIPUR NATIONAL UNIVERSITY, JAIPUR

SUBMITTED BY
SUBMITTED To- NITESH KUMAR
Dr. SUDHIR KR. GARG SHUBHAM JAIN
HOD OF CHEMICAL 4 TH YEAR (CHEMICAL ENGG)
 CONTENTS
BEGINNING OF PETROLEUM REFINING IN INDIA
HISTORY OF IOCL
REFINERY IN INDIA
INTRODUCTION TO MATHURA REFINERY
REFINERY PROCESSES
COMPOSITION OF CRUDE OIL
TYPES OF CRUDE OIL
PROCESS UNIT IN MATHURA REFINERY
ATMOSPHERIC AND VACUUM DISTILLATION UNIT
(AVU)
AVU FLOW SHEET
PRODUCTS FROM MATHURA REFINERY
CATALYTIC REFORMING UNIT (CRU)
CRU FLOW SHEET
 PRESENTATION ON
VOCATIONAL
TRAINING IN
IOCL, MATHURA

dian Oil Corporation Ltd

athura Refinery-281005
P, India.
 BEGINNING OF PETROLEUM REFINING IN
INDIA
The first refinery, started in
1861, produced kerosene by
simple atmospheric distillation
In 1890s Crude Oil used to be
distilled in DIGBOI in Cast Iron
pans called Stills.

Bottom portion of one such still

of 9 feet dia is still kept at
Digboi Refinery.
The refinery was commissioned
THE FIRST STILL
in 1901 at Digboi with 500 LIES STILL
Barrels per Day capacity
INDIAN OIL CORPORATION
LIMITED (IOCL)
Indian Refineries Ltd. was set-up in August, 1958, as
a state owned company to manage refineries.

Indian Oil Company was set-up in July, 1959 as a

state owned Marketing company.

The above two companies were merged on 1st

September, 1964 to form Indian Oil Corporation
Limited.

Indian Oil is the highest ranked Indian company in

the Fortune Global 500 listing, at the 83rd position in
2012.

It is also the 18th largest petroleum company in the

Indian IOC
- Operates 10 of Indias 22 refineries

Refineries - Groups refining Capacity: 65.7 MMTPA

Largest in the country
- 40.4% refining share in the country

BHATINDA
Refineries No. PANIPAT
(9.0)
MMTPA (12.0) BONGAIGAON DIGBOI
IOC Group 10 65.7 (2.35) (0.65)
BPC group 4 30.5 MATHURA
HPC 3 23.8 (6.0)
ONGC/MRPL 2 GUWAHATI NUMALIGARH
BARAUN (3.0)
15.08 (1.0)
I
RIL (Pvt.) 2 (6.0)
60.0 BINA
ESSAR 1 18.1 BARODA
(6.0)
JAMNAGAR
(13.7) HALDIA
(RIL 33.0 )
(6.0)
ESSAR 18.1) PARADEEP
MUMBAI (15.0)
(BPC 12.0) VISAKH
(HPC 6.5) (8.5)

TATIPAKA
MANGLORE (0.08 )
(11.82 )
CHENNAI
Existing IOC
(10.5)
Total capacity in Subsidiaries of
KOCHI
IOC
the country: (9.5 ) NARIMANAM Others
(1.0)
213.18 MMTPA New / Additions
REFINERY IN INDIA
The first refinery in India, Digboi Refinery was
commissioned in 1901

Guwahati Refinery was commission on 01.01.1962

Barauni Refinery was commissioned in July, 1964

Koyali Refinery was commissioned in Oct, 1965

Haldia Refinery was commissioned on 01.01.1975

Mathura Refinery was commissioned in March 1982

Panipat Refinery was commissioned in October, 1998

 MATHURA REFINERY
Mathura Refinery, the sixth refinery of
Indian Oil was commissioned in 1982
with a capacity of 6.0 MMTPA.
Mathura Refinery is the first in Asia and
third in the world to receive the coveted
ISO-14001 certification for Environment
Management System in 1996.
It is also the first in the World to get
OHSMS certification for Safety
Management in 1998.
 REFINERY PROCESSES

An oil refinery separates the

crude oil in to different fractions
and converts them into usable
products
Maximize Higher value
distillates like LPG, gasoline,
ATF, Kerosene and Diesel
Produce cleaner products
COMPOSITION OF CRUDE OIL
Crude oils is a complex mixture of
thousands of hydrocarbons. (i.e
paraffins, Napthenes & Aromatics)
Brownish black in colour and colloidal
in nature.
Contains small amounts of non-
hydrocarbon impurities in the form of
organic compounds of sulphur,
oxygen, nitrogen, metals, water and
salts.
 TYPES OF CRUDE OIL

LOW SULPHUR

Indian: Bombay High

Nigerian: Girasol, Farcados, Bonny light

HIGH SULPHUR

Arab Mix, Kuwait, Dubai, Ratawi, Basra

etc
 ELEMENT COMPOSITION OF
CRUDE OIL
Hydro Carbons > 95%
Sl. no. Element Percentage (%)

1 Carbon 83-87

2 Hydrogen 11-15

3 Sulphur 0-3

4 Oxygen 0-2

5 Nitrogen 0-0.6

6 Metals 0-0.1
PROCESS UNIT IN MATHURA REFINERY
Atmospheric and Vacuum unit (AVU)
Catalytic Reforming unit (CRU)
Fluid Catalytic Cracking unit (FCCU)
Merox unit
Propylene Recovery unit (PRU)
Bitumen Blowing unit (BBU)
Diesel Hydro Desulphurization unit (DHDS)
Diesel Hydro-Treatment unit (DHDT)
Hydrogen Generation unit (HGU)
Sulphur Recovery unit (SRU)
Amine Recovery unit (ARU)
Motor Spirit Quality unit (MSQ)
Prime G
 ATMOSPHERIC AND VACUUM
DISTILLATION UNIT (AVU)

The ADU (Atmospheric

Distillation Unit)
separates most of the
lighter end products
such as gas, gasoline,
naphtha, kerosene, and
gas oil from the crude
oil.
The bottoms of the ADU
are then sent to the
VDU (Vacuum
Distillation Unit).
AVU FLOW SHEET
 PRODUCTS FROM MATHURA
REFINERY
SHORT NAME LONG NAME

Gas Fuel gas

LPG Liquefied Petroleum Gas
NAP Naphtha
HN Heavy Naphtha
KERO Kerosene
ATF Aviation Turbine Fuel
LGO Light Gas Oil
HGO Heavy Gas Oil
VD Vacuum Diesel
LVGO Light Vacuum Gas Oil
LDO Light Diesel Oil
HVGO Heavy Vacuum Gas Oil
VR Vacuum Residue
CATALYTIC REFORMING UNIT
(CRU)
OBJECTIVE : To Upgrade the Naphtha
to High
Octane MS Component
(Reformate).
FEED : 85-160 Deg C cut Naphtha/
Visbreaker Naphtha
CATALYST : Ni-Mo Oxides for NHTU
Reactor
Pt-Snor Re for Reforming
CRU FLOW SHEET
 UNIT SUBDIVISION
The whole CRU can be divided into
three subunits as:

Naphtha Splitting Unit (NSU)

Naphtha Hydro-treater Unit (NHU)
Catalyst Reforming Unit CRU &
Continuous Catalyst Regeneration
Unit-CCRU
CATALYTIC REFORMING UNIT CRU
&CONTINUOUS CATALYST
REGENERATION UNIT- CCRU
Catalytic reforming is normally facilitated by a bi-
functional catalyst that is capable of rearranging and
breaking long-chain hydrocarbons as well as removing
hydrogen from naphthenes to produce aromatics.
the idea of a Catalytic Reforming Unit is to have RON
(Research Octane Number) as high as possible at the
same time keeping the Olefins, Benzene & Aromatics
under the specified limits.
The different types of reformers are classified as a fixed-
bed type, semi regenerative type, cyclic type and the
continuous regenerative type.
This classification is based on the ability of the unit to
operate without bringing down the catalyst for
Regeneration.
 CATALYTIC REFORMING UNIT
CRU
A catalytic reforming process converts a feed
stream containing paraffins, Olefins and
naphthene to aromatics.
The product stream of the reformer is
generally referred to as reformate.
The purpose of the CR unit is to produce a
high octane no. reformate as a blending stock
for the production of motor spirit.
The octane no. of the gasoline coming from
the AVU is around 66, whereas the required
value of the octane no. is 87, 88 and 93.
 REFERENCES

Dr. Ramprasad, Petroleum Refining Technology

en.wikipedia.org
www.britannica.com
www.iocl.com
www.kbr.com
Guide to Refining from Chevron Oil's website
Behind high gas prices: The refinery crunch
Gary, J.H. and Handwerk, G.E. (1984).
Petroleum Refining Technology and Economics
(2nd Edition ed.).
THANKING YOU