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Solvent Extraction
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Solvent Extraction
Replace concentration with moles over volume
and let q equal the fraction in the aqueous phase
Define a new term for the ratio of the
volumes of the phases
We can do a little algebra and find an
expression for q
Since if it does not end up in the aqueous phase it
must be in the organic.
Giving
Sample Problem
System I
Da = 32 Db = 0.032 (A ratio of 1000)
Vr= 1
Let's recall our equations
q (fraction in aqueous) = 1 / (DVr + 1)
p (fraction in organic) = DVr / (DVr + 1)
Vr (volume ratio) = Vo / Va
Case I
Once we have selected the solvent and pH, then there is little
that we can do to change D. What else do we have in our
control?????
Let's look
p = DVr / (DVr + 1)
Not much here except Vr and in fact that is the key to this
problem. Is there an optimum Vr value for the values of D that
we have? Yes!
Our equation for this is V r(opt) = (Da*Db)-0.5
Revisit the two cases
Case II
Da = 1000 and Db = 1
Vr (opt) = (1000*1)-0.5 = 1000-0.5 = 0.032
Which mean that when we do our extraction
we will extract _______ mL of organic for
each _______ mL of aqueous.
Purity for Case II
Which will give us the 97% purity we had for Case I with with the Vr of 1.
Can we improve this purity?
If we were to extract again then we would just
remove the same proportions. We would get
more compound extracted but it would be the
same purity.
pa = 0.97
pb = 0.03
qa = 0.03
qb = 0.97
.
Before Shaking Amount A Amount B
Organic Phase 0.97 0.03
Fresh Aqueous Phase 0 0
Now we extract shake shake shake
Rotate the
apparatus counter
clockwise about 90o
to 100o.
Craig CCE
Tube# 0 1 2 3 4
Organic
0
Phase
Aqueous
1 0 0 0 0
Phase
Tube# 0 1 2 3 4
Organic Phase p
Aqueous Phase q 0 0 0 0
Transfer Step 1
Tube# 0 1 2 3 4
Organic Phase 0 p
Aqueous Phase q 0 0 0 0
Now here is what is in each tube/phase after equilibrium is reached.
Tube# 0 1 2 3 4
Organic
pq pp
Phase
Aqueous
qq qp 0 0 0
Phase
Now we do Transfer 2
Tube# 0 1 2 3 4
Organic Phase 0 pq pp
Aqueous Phase q2 pq 0 0 0
Now here is what we have in each tube after the next equilibrium.
The total in each tube times either p or q as appropriate.
Tube# 0 1 2 3 4
Organic
pq2 p*2pq p3
Phase
Aqueous
q3 q*2pq qp2 0 0
Phase
We transfer again.
Transfer Step 3
Tube# 0 1 2 3 4
Organic Phase 0 pq2 2p2q p3
Aqueous Phase q3 2pq2 p2q 0 0
Shake Again Equilibrium 4
Tube# 0 1 2 3 4
Organic
pq3 p*3pq2 p*3p2q p4
Phase
Aqueous
q4 q*3pq2 q*3p2q q*p3 0
Phase
Transfer 4
Tube# 0 1 2 3 4
See a trend????
Craig CCE
Or the formula
Horrible Yield!
Craig CCE
http://www.chem.uoa.gr/applets/AppletCraig/Appl_Craig2.html
Final Formulas(1)