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SECTION 5 LESSON 4
Content
The iGCSE
Section 1 Principles of Chemistry
Chemistry
course Section 2 Chemistry of the Elements
Section 5
a) Extraction and uses of
metals
Chemistry b) Crude oil
in industry c) Synthetic polymers
d) The industrial manufacture
of chemicals
d) The industrial manufacture of chemicals
Lesson 4 5.22 understand that nitrogen from air, and hydrogen from natural gas or the
cracking of hydrocarbons, are used in the manufacture of ammonia
5.23 describe the manufacture of ammonia by the Haber process, including the
essential conditions:
d) The industrial i a temperature of about 450C
ii a pressure of about 200 atmospheres
manufacture iii an iron catalyst
of chemicals 5.24 understand how the cooling of the reaction mixture liquefies the ammonia
produced and allows the unused hydrogen and nitrogen to be recirculated
5.25 describe the use of ammonia in the manufacture of nitric acid and fertilisers
5.26 recall the raw materials used in the manufacture of sulphuric acid
5.27 describe the manufacture of sulphuric acid by the contact process, including
the essential conditions:
i a temperature of about 450C
ii a pressure of about 2 atmospheres
iii a vanadium(V) oxide catalyst
5.28 describe the use of sulphuric acid in the manufacture of detergents, fertilisers
and paints
5.29 describe the manufacture of sodium hydroxide and chlorine by the electrolysis
of concentrated sodium chloride solution (brine) in a diaphragm cell
5.30 write ionic half-equations for the reactions at the electrodes in the diaphragm
cell
5.31 describe important uses of sodium hydroxide, including the manufacture of
bleach, paper and soap; and of chlorine, including sterilising water supplies and in
the manufacture of bleach and hydrochloric acid.
1. The Haber
Process
- Ammonia, NH3
The Industrial
Manufacture of
Chemicals
Whats
this all
about?
#1 The Haber Process
The nitrogen-rich
fertiliser ammonium
nitrate is used regularly
by farmers, and spread
in huge quantities on
crops around the world.
#1 The Haber Process
The
Basics!
#1 The Haber Process
The
Basics!
Reversible reaction
#1 The Haber Process
The
Basics!
Industrial Conditions:
TEMPERATURE: 450oC
CARALYST: Iron
#1 The Haber Process
Reaction vessel
Trays of iron
catalyst
450oC and
200 atm
Condenser
#1 The Haber Process
H2 and N2
mixed in 3:1
Reaction vessel
ratio
450oC and
200 atm
Condenser
#1 The Haber Process
H2 and N2
mixed in 3:1
Reaction vessel
ratio
450oC and
200 atm
Condenser
#1 The Haber Process
H2 and N2
mixed in 3:1
Reaction vessel
ratio
Liquid ammonia
#1 The Haber Process
H2 and N2
mixed in 3:1
Reaction vessel
ratio
#2 Making Ammonium
Nitrate fertiliser
Two important
reactions
involving ammonia
The Industrial
Manufacture of
Chemicals
Conditions:
Catalyst (vanadium oxide)
Pressure of 2 atmospheres
Temperature of about 450oC
The Contact Process
Three stage process.
The Contact Process
Three stage process.
1. Preparation of sulphur dioxide
Sulphur is burnt in
air (or sulphur ore
may be used)
The Contact Process
Three stage process.
1. Preparation of sulphur dioxide
2SO
2 stages: (a) +
sulphur (s)
the O
oxide is 2(g) 2SO
(b) The oleum is
3(g)
then diluted to
dissolved in conc give conc sulphuric
3. Preparation of sulphuric acid
sulphuric acid to
produce oleum
acid which is 98%
acid and 2% water
2SO
2 stages: (a) +
sulphur (s)
the O
oxide is 2(g) 2SO
(b) The oleum is
3(g)
then diluted to
Sulphurdissolved
oxidein(SO conc 3) cannot be added to water
give conc sulphuric
directly since the
acidreaction is violent and dangerous
3. Preparation
sulphuric
produce oleum of sulphuric
to
acid
acid and
acid which
2% water
is 98%
Synthetic
Paints
fibres
Car
Drugs H2SO4 batteries
Dyes Plastics
Detergents
1. The Haber
Process
- Ammonia, NH3
The Industrial
Manufacture of
Chemicals
+ -
Sodium hydroxide,
chlorine and hydrogen
are all produced by
the electrolysis of
brine (salt sodium
chloride dissolved in
water)
Titanium Steel
anode cathode
diaphragm
Manufacture of sodium hydroxide and chlorine
+ -
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
brine (salt sodium solution
chloride dissolved in
water)
(brine)
Titanium Steel
anode cathode
diaphragm
Manufacture of sodium hydroxide and chlorine
+ -
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
brine (salt sodium solution
chloride dissolved in
water)
(brine)
+ -
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
NaCl Na+ Cl-
brine (salt sodium solution
chloride dissolved in
water)
(brine)
+ -
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
NaCl Na+ Cl-
brine (salt sodium solution
chloride dissolved in
water)
(brine)
Cl-
+ -
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
NaCl Na+ Cl-
brine (salt sodium solution
chloride dissolved in
water)
(brine)
Cl-
Chlorine gas
+ -
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
NaCl Na+ Cl-
brine (salt sodium solution
chloride dissolved in
water)
(brine)
Cl-
Chlorine gas
+ -
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
NaCl Na+ Cl- H2O H+ OH-
brine (salt sodium solution
chloride dissolved in
water)
(brine)
Cl-
Chlorine gas
+ -
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
NaCl Na+ Cl- H2O H+ OH-
brine (salt sodium solution
chloride dissolved in
water)
(brine)
Cl- H+
Chlorine gas
+ -
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
NaCl Na+ Cl- H2O H+ OH-
brine (salt sodium solution
chloride dissolved in
water)
(brine)
Cl- H+
Chlorine gas
+ - Hydrogen gas
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
NaCl Na+ Cl- H2O H+ OH-
brine (salt sodium solution
chloride dissolved in
water)
(brine)
Cl- H+
Chlorine gas
+ - Hydrogen gas
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
NaCl Na+ Cl- H2O H+ OH-
brine (salt sodium solution
chloride dissolved in
water)
(brine)
Chlorine gas
+ - Hydrogen gas
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
NaCl Na+ Cl- H2O H+ OH-
brine (salt sodium solution
chloride dissolved in
water)
(brine)
Chlorine gas
+ - Hydrogen gas
Sodium hydroxide,
chlorine and hydrogen Concentrated
are all produced by sodium
the electrolysis of chloride
NaCl Na+ Cl- H2O H+ OH-
brine (salt sodium solution
chloride dissolved in
water)
(brine)
Manufacture
of bleach
Manufacture
of chlorine NaOH Manufacture
of paper
Manufacture
of
hydrochloric
acid Manufacture
of soap
1. The Haber
Process
- Ammonia, NH3
The Industrial
Manufacture of
Chemicals