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CONCENTRATION TECNOLOGIES
To Final Product
Principles of Flotation
Flotation concentration method utilizes
the differences in physico chemical
surface properties of particles.
Hydrophobic (water repellent) particles
float with air bubbles to form a froth.
Wetted hydrophilic particles sink.
Hydrophobicity increases with the
contact angle btw particles and bubbles.
Chemical reagents are used in flotation.
Flotation is a selective separation
process.
Flotation is the most important and
versatile mineral processing technique
used in mining industry.
APPLICATION OF FLOTATION
Examples include:
triphylite Li(Fe,Mn)PO4
monazite (Ce,La,Y,Th)PO4
Apatite group Ca5(PO4)3(F,Cl,OH)
hydroxylapatite Ca5(PO4)3OH
fluorapatite Ca5(PO4)3F
chlorapatite Ca5(PO4)3Cl
pyromorphite Pb5(PO4)3Cl
vanadinite Pb5(VO4)3Cl
erythrite Co3(AsO4)28H2O
amblygonite LiAlPO4F
lazulite (Mg,Fe)Al2(PO4)2(OH)2
wavellite Al3(PO4)2(OH)35H2O
turquoise CuAl6(PO4)4(OH)85H2O
autunite Ca(UO2)2(PO4)210-12H2O
carnotite K2(UO2)2(VO4)23H2O
phosphophyllite Zn2(Fe,Mn)(PO4)24H2O PO43- anion
DEPOSITS
Rock phosphate can also be found on
USA, Egypt, Israel, Morocco, Navassa
Island, Tunisia, Togo, S. Arabia and
Jordan have large phosphate mining
industries as well.
USE OF PHOSPHATE
Phosphates were once commonly used in laundry detergent in the form trisodium
phosphate (TSP), but, because of algae boom-bust cycles tied to emission of phosphates
into watersheds, phosphate detergent sale or usage is restricted in some areas.
In agriculture, phosphate is one of the three primary plant nutrients, and it is a component
of fertilizers. Rock phosphate is quarried from phosphate beds in sedimentary rocks. In
former times, it was simply crushed and used as is, but the crude form is now used only in
organic farming. Normally, it is chemically treated to make superphosphate, triple
superphosphate, or ammonium phosphates, which have higher concentration of
phosphate and are also more soluble, therefore more quickly usable by plants.
Fertilizer grades have three numbers; the first is the available nitrogen, the second is the
available phosphate (expressed on a P2O5 basis), and the third is the available potash
(expressed on a K2O basis). Thus a 10-10-10 fertilizer would contain ten percent of each,
with the remainder being filler.
Surface runoff of phosphates from excessively-fertilized farmland can be a cause of
phosphate pollution, leading to eutrophication (nutrient enrichment), algal bloom, and
consequent oxygen deficit. This can lead to anoxia for fish and other aquatic organisms in
the same manner as phosphate-based detergents.
Phosphate compounds are occasionally added to the public drinking water supply to
counter plumbosolvency.
The food industry uses phosphates to perform several different functions. For example, in
meat products, it solubilizes the protein. This improves its water-holding ability and
increases its moistness and succulence. In baked products, such as cookies and crackers,
phosphate compounds can act as part of the leavening system when it reacts with an
alkalai, usually sodium bicarbonate (baking soda).
Phosphate minerals are often used for control of rust and prevention of corrosion on
ferrous materials, applied with electrochemical conversion coatings
PHOSPHATE FLOTATION
Collophane, the principal phosphate mineral occuring in the phospate
deposits of the Southeastern US, floats readily with crude fatty acids
and soaps, fuel oil and soda ash, caustic soda or amonia.
Double flotation method is used in US Florida plants by using both
fatty acid and amine types of collectors.
Single flotation is employed at N.Africa and Middle Eastern
phosphate operations by using either a fatty acid or an amine type of
collector.
Cytecs Aero 727, 727J and 728 promoters have been successfully
used where only fatty acid float approach is practiced.
Cytecs Aero 8651 fatty amine promer is utilized in operations running
an amine float.
In the reverse flotation, Cytec Acco-Phos 950 depressant (20-100 g/t)
minimizes phosphate loses into the silica froth product using amine
collectors.
In the treatment of sedimentary pebble phosphates, Aero 845 can be
used in conjuction with fatty acids.
US DOUBLE PHOSPHATE FLOTATION
FEED -
Slimes (-10 )
Desliming
(Hydrocyclones)
+
conditioner
Phosphate-
70%S
Silica Sep. Flot
F T
Rougher fl. Silica (final tails)
pH=9-9.5
C
(sodaash/NaOH)
Conditioning with
Crude fatty oil Silica Removal Reverse
H2SO4+washing Flot.
Fuel-oil
to remove reagents Cleaner fl. Phosphate
Conc.
pH=6.5-7
conditioner
Fatty/ether amine Silica (gangue)
LIME STONE/CALCITE
Limestone is a sedimentary rock
composed largely of the mineral
calcite (calcium carbonate: CaCO3).
l
Limestone often contains variable
amounts of silica in the form of
chert or flint, as well as varying
amounts of clay, silt and sand as
disseminations, nodules, or layers
within the rock.
USES OF LIMESTONE
Iron impregnations in limestone
R=100% pH:6- 9
recovery, % 80
60
fluorite calcite apatite
40
20
R=0%
No flot.
0 -06 -05 -04 -03
10 10 10 10
sodium oleate concentration, mol/dm3
Mole/l
Graphite can be ground to a fine powder for use as a slurry in oil drilling;
in zirconium silicate, sodium silicate and isopropyl alcohol coatings for
foundry molds; and for calcined petroleum coke, which is used as a
carbon raiser in the steel industry.
Direct flotation of iron ores was practiced for many years using
Aero899R promoter (1-2 kg/t) along with number 5 fuel oil at pH 3-5
adjusted by H2SO4 following high solids conditioning.
Iron pellets
HEAVY MINERAL SANDS
Primary Deposits
Feldspar 20-30% Kaolin
alteration
Mica Cormwall/UK
Granite
Syanite KAOLIN
Porphyr
Sedimantary
Quartz Deposits
Ilmenite Georgia/USA
LIBERATION OF KAOLIN
Liberation size for KAOLIN 4-6 m.
Liberation size for FELDSPAR 200-300 m.
Liberation size for QUARTZ 700 m.
Before concentration:
For soft kaolinsAttrition scrubbing for dispersing clays
For hard kaolinscrushing/grinding are required.
(Due to remaining fine silica product, quality is low)
CLASSIFICATION CONCENTRATION
DRY (Crushing+dry grinding+air classification)
(requires selective mining operation)
WET (Magnetic separation+flotation+hydrocyclones)
(complex flowsheet, but product quality is very high)
The production process includes:
disintegration and classification,
hydrocycloning, thickening, filter-
pressing and drying. Product range:
kaolin for ceramic, kaolin for paper,
glass silica sand, dry and wet classified
silica sand, ground kaolin, chamotte.
Process
The extraction plant is situated adjacent to the quarrying operation to enable the waste to
be returned to backfill.
Crude kaolin from the quarry is first made into a slurry with water. This slurry passes
through a series of washing and classification steps in order to remove the quartz and
mica impurities. This results in a pure kaolin product which is completely devoid of free
silica.
The kaolin is filtered in filter presses and the filter cake is pressed into pellet form prior to
drying in gas-fired dryers. The final kaolin pellets contain 10% moisture on average. These
are packaged and despatched to customers in the ceramic, paint, paper and other
industries.
A dry powder product is also produced for those industries that cannot tolerate moisture,
such as the rubber, plastic and pesticide industries. The dry powder is produced by
passing the kaolin pellets through an attritor and classifier with simultaneous drying with
hot air.
Water from the drying process is recovered and recycled to the extraction plant through a
return water pipeline.
MAJOR IMPURITIES
(Kaolin is used in fine size range. Flotation efficiency diminishes with the
size of particles. Kaolin is used as a white pigment thus colored
impurities must be removed).
Iron oxides
KAOLIN FLOTATION
80
DDA
recovery, %
60
fluorite
40
NaOl
20
0
2 4 6 8 10 12 14
pH
NaOl - sodium oleate, DDA-dodecylamine,
SDS,- sodium dedecyl sulfite
Class 5. Sparingly soluble salts
100
chrysocolla
80
calcite
recovery, %
60
40 bastnesite
20
barite
0
0 2 4 6 8 10 12 14
pH
80
flotation recovery, %
QUARTZ
60
40
18 16 14 12 10 8 6 4
20
60
40
20 Na 2SO4 NaCl