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Review Session
Example: 4dxy ?
Radial distribution function; penetration and shielding
Mathematical functions relevant to atomic orbitals:
Radial wavefunction
Probability density
Radial distribution function
4r
Example:
3s electron of Na0 and
2p electron of Na+?
Reading term symbols
Know your formulas and the systems quantum numbers:
Example:
d4 configuration?
d6 configuration?
Finding excited term symbols from the microstate table
For a p configuration:
Periodic trends
Know the trends in:
Atomic radii
Ionization energies
Electron affinity
Electronegativity (know the
difference between the
Pauling, the Mulliken and the
Allred-Rochow definitions)
Simple Bonding Theory and Symmetry
Hybridization
Hybridization is a simple model
that helps to explain molecular
geometries
In reality, d orbitals are not
usually used in bonding of main-
group compounds (Why?)
Bents Rule
Bents rule (IUPAC Gold Book definition):
In a molecule, smaller bond angles are formed between
electronegative ligands since the central atom, to which the ligands
are attached, tends to direct bonding hybrid orbitals of greater p
character towards its more electronegative substituents.
2 lone pairs
SN = 6
1 lone pair
SN = 5
F
F
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