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Resonators carried by
molecules may be the origin
of Hendrik A. Kramers
Virtual oscillator model
The requirement of the
On the other hand, Einsteins first latter theorem, as well
quantum theory was connected, as the avoidance of
through its application to the Gibbs paradox led
problem of specific heats, with Einstein to construct the
Nernsts theorem, i.e. the third law quantum theory of the
of thermodynamics. ideal gas in 1924-1925,
when he applied to the
ideal gas the same
This theory stimulated Erwin statistics that Styendra
Schrodinger to look seriously into de N. Bose applied to the
Broglies theory of matter waves, thermal radiation.
which subsequently led Schrodinger
to construct his wave mechanics in
1926.
The most important steps
in the construction of
quantum mechanics were Bohrs attention was
made, not by Bohr, but by concentrated on internal
Einstein. electronic processes in atoms
and molecules, supplemented
by some philosophical
considerations thereupon.
This pecualirity must be
closely related to his early
studies in Britanian at
Thomsons and Rutherfords
laboratories.
On the other hand, Einsteins
concern spreads so wide from
the physical chemistry to the
space time structure that his He inherited these concerns
aim was to construct a fromreading books and
consistent theory that was articles by Kirchhoff,
substainable from every point of Helmholtz, Hertz, Wien,
view. Boltzmann and Planck
He also frequently discussed
chemical and thermal effects in
the material sciences.
The chemico-termal
tradition
Even his attempt at the special theory of
relativity seems not unrelated to his aim of
constructing quantum theory.
Moreover, he had in mind up to the end of his
life the hope of constructing his own theory of
the microscopic world from his unified field
theory.
Heisenberg :
In the course of scientific progress it can happen that a new
range of empirical data can be completely understood only when
enormous effort is made to change ones philosophical
framework and to change the very structure of the thought
process. In the case of quantum mechanics, Einstein was no
longer willing to take this step, or perhaps no longer able to do
so.
Arthur Fine :
It is Bohr who emerges the conservative, unwilling (or unable?)
to contemplate the overthrow of the system of classical concepts
and defending it by recourse to those very conceptual
necessities and a priori arguments. [. . . ] Whereas, with regard
to the use of classical concepts, Einsteins analytical method kept
him ever open-minded.
In the fifth (1927) and the sixth (1930) Solvay
conferences, Einstein and Bohr exchanged discussions
on their views of quantum mechanics. This discussion
is described in Bohrs memoirs expressing the latters
triumph.
Einstein in a letter to Lorentz :
If the state function were interpreted as expressing probabilities
for finding properties of an individual system, then the
phenomenon of the collapse of the wave packet would represent
a peculiar action-at-a distance. [. . . ] It represents a peculiar
nonlocalized mechanism, which violates relativity. [. . . ] These
problems are not of the theory itself but of the interpretation
according to which the theory gives a complete statistical
description of individual systems. The alternative is to interpret
the state function as providing information only about the
distribution of an ensemble of systems and not about features of
the individual system themselves.
Einstein in a letter to Sommerfeld :
On Quantum Mechanics I think that, with respect to
ponderable matter, it contains roughly as much truth as
the theory of light without quanta. It may be a correct
theory of statistical laws, but an inadequate conception of
individual elementary processes.
During these two conferences, Bohr rebutted
Einsteins argument using the doctrine of
disturbance, starting that certain simultaneous
determinations were not possible because any
one of them would inevitably disturb the
physical situation so as to preclude the other.