Professional Documents
Culture Documents
Analytical Chemistry
Redox Titrimetry and Potentiometry
Electrochemistry
Oxidation/Reduction Reactions
Redox reactions involve electron transfer
from one species to another
Ox1 + Red2 Red1 + Ox2
Ox1 + ne- Red1 (Reduction
reaction)
Red2 Ox2 + ne- (Oxidation
reaction)
Reducing agent donates electrons (is
oxidized)
Oxidizing agent accepts electrons (is
reduced)
Electrochemistry
Oxidation/Reduction Reactions
Typical oxidizing agents: Standard
Potentials,V
O2 + 4H+ + 4e- 2H2O
+1.229
Ce4+ + e- Ce3+ +1.6
(acid)
MnO4- + 8H+ + 5e- Mn2+ + 4H2O +1.51
Typical reducing agents:
Zn2+ + 2e- Zno -0.763
Cr3+ + e- Cr2+
-0.408
Na+ + e- Nao -2.714
The salt bridge allows charge transfer through the solution and prevents mixing.
The spontaneous cell reaction (Fe2+ + Ce4+ = Fe3+ + Ce3+) generates the cell potential.
The cell potential depends on the half-reaction potentials at each electrode.
The Nernst equation describes the concentration dependence.
A battery is a voltaic cell. It goes dead when the reaction is complete (Ecell = 0).
Gary Christian,
Gary Christian,
Analytical Chemistry,
6th Ed. (Wiley)
Makes electrical
contact with glass,
and sets potential of
ref. electrode.