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LECTURE 10-11
Refrigerants
2
Introduction
Refrigeration : Transfer of heat from lower temperature to higher
temperature
4
Refrigerators and Heat Pumps
Heat flows from high temperature to lower
temperature, reverse is possible with the help
of external device
Working fluid is refrigerant
Heat pump and refrigerators are same devices,
only difference is objective
at worst heat pumps = resistance heaters
5
Refrigerators and Heat Pumps
R = Refrigeration
HP = Heat Pump
6
Refrigerators and Heat Pumps
Cooling capacity is measured in tons of refrigeration
7
Reversed Carnot Cycle
8
Ideal Vapor Compression Cycle
9
Ideal Vapor Compression Cycle
Non Ideal process,
enthalpy is constant
10
Ideal Vapor Compression Cycle
Steady flow energy equation (SFEE)
11
Solved Example
12
Solved Example
13
Solved Example
14
Solved Example (Heat Pump)
Example: A vapor-compression heat pump cycle with R-134a as
the working fluid maintains a building at 20oC when the outside
temperature is 5oC. The refrigerant mass flow rate is 0.086 kg/s.
Additional steady state operating data are provided in the table.
Determine the
(a) compressor power, in kW,
TH = 293 K (20oC)
(b) heat transfer rate provided to the TC = 278 K (5oC)
building, in kW,
(c) coefficient of performance.
State 1 2 3
h (kJ/kg) 244.1 272.0 93.4
15
Solved Example (Heat Pump)
State 1 2 3
h (kJ/kg) 244.1 272.0 93.4 TH = 293 K (20oC) TC = 278 K (5oC)
kg kJ 1 kW
Wc 0.086 (272 .0 244 .1) 2.4 kW
s kg 1 kJ/s
(b) The heat transfer rate provided to the building is
Q out m
(h2 h3 )
kg kJ 1 kW
Qout 0.086 (272 .0 93 .4) 15.4 kW
s kg 1 kJ/s
16
Solved Example (Heat Pump)
State 1 2 3
h (kJ/kg) 244.1 272.0 93.4 TH = 293 K (20oC) TC = 278 K (5oC)
Q out 15.4 kW
COP COP 6.4
Wc 2.4 kW
18
Home Work
19
Home Work
20
Refrigerants
Most refrigerants are halogenated hydrocarbons. The naming convention
adopted by ASHRAE is,
R(a-1)(b+1)d = CaHbClcFd c = 2(a 1) b d
a 1 0 a 1 H
b 1 2 b 1
d 2 F C F chlorodifluoromethane
c 2 a 1 b d
c 2 1 1 1 2 1 Cl
21
Refrigerants
Refrigerant selection is based on several factors:
Performance: provides adequate cooling capacity cost-effectively.
Safety: avoids hazards (i.e., toxicity).
Environmental impact: minimizes harm to stratospheric ozone layer and
reduces negative impact to global climate change.
22
Refrigerant Types and Characteristics
Global Warming Potential (GWP) is a simplified index that estimates the potential
future influence on global warming associated with different gases when released
to the atmosphere. 23