8

8.1 8.3

Tafel










8.2


8.1

1.
2. Tafel
3.
4.
5.
6.
7.
8.1 Tafel

Tafel
 8.1 Tafel

OL(EO)40Zn1.0M HCl1.0M H2SO4Tafel R

8.1

 8.1

FeCr12pH12.515g/LCl
R
8.1

Nyquist
 8.1

70/30 Cu-NiabNyquist

R
 8.1

RS
Cdl
Q1CPE1CPE
Q2CPE2
CPE
Rf
Rout

Q3CPE3
CPE
Rfin

WWarburg

70/30 Cu-Ni R
8.1

8.1

2

RS Rctg
Rctg 2
R lim RS
2

1 f Rctg C
n 2 2 2
f 0

 8.1

Reactivity of
polyester
aliphatic amine
surfactants as
corrosion
inhibitors for
carbon steel in
formation
water

200ppmMA
C4H2O3BPM=5000X+Y10
RRC10H21C12H25C14H29C16H33
 8.1

R
TCMFP10mass
CCCl
8.2

8.2.1

8.2.1

Structure
and
composition
effects on
pitting
corrosion
resistance of
austenitic
stainless
steel after
molybdenu
m ion
implantation

Mo+0.9NaCl37
8.2.1

Electrochemica
l methods for
evaluating
inhibitors of
steel corrosion
in concrete

8.2.1

Electrochemica
l methods for
evaluating
inhibitors of
steel corrosion
in concrete
0.5mol/LNaCl

8.2.1

Electrochemica
l methods for
evaluating
inhibitors of
steel corrosion
in concrete

8.2.1

Electrochemica
l methods for
evaluating
inhibitors of
steel corrosion
in concrete
0.5mol/LNaCl

 8.2.2
1

ASB1.1V 25min1.5V 5min

ASB
ECBASB

RH<30%
a20minb6h
Evolution of passivity in air exposure of an iron passive film.
Electrochimica Acta, 2006, 52(1): 187-193
8.2.2
1

ECB ECB
20min
282 a<20minb>6h282
8.2.2
2

AISI 304LAISI 304LNaOH 0.1M110.1M

NaOH+0.5M NaCl
AB1mV/s
R
8.2.2
2

Mohammed A Amin,
Sayed S Abd El Rehim,
Essam E F El Sherbini.
AC and DC studies of
the pitting corrosion of
Al in perchlorate
solutions.
Electrochimica Acta,
2006, 51(22): 4754-
4764

Al0.25M NaClO45mV/s25
8.2.2
3

/2

i15215
325435
545655

Al0.25M NaClO425
8.2.2
3

Al0.25M NaClO4
25
8.2.2
3

Al0.25M NaClO425
(1)0.57V(2)0.50V(3)0.43V(4)0.35V(5)0.31V(6)
0.26V(7)0.2V(8)0.19V(9)0.18V(10)0.17V(11)0.16V
(12)0.15V
8.2.2
3

Al0.25M NaClO4
8.2.2
3

Al0.25M NaClO4
25
8.2.2
3

Al0.25M NaClO4
 8.2.2
3

2024Al0.5M NaCl
Study of electrochemical behavior and morphology of pitting on anodized 2024
aluminum alloy. Surface and Coatings Technology, 2004, 182(2-3): 237-241
8.2.2
4

aRQCPEbR1Q
CPEZf
cR1Q1CPEQ2
CPEdR1Q1CPER2Q2
CPE
Passivation model of 316 stainless steel in simulated cooling water and the effect
of sulfide on the passive film
8.3

8.3.1

1
2
3
4



5
 8.3.2

Corrosion protection by organic coatings:
electrochemical mechanism and novel methods of
investigation
8.3.2

8.3.2

 8.3.2

a b

ab

Evaluation of the surface treatment effect on the corrosion performance of paint coated
carbon steel
 8.3.2

abc
New methods for the study of organic coatings by EIS: New insights into attached
and free films
8.3.3

G Grundmeier, W Schmidt, M Stratmann.

Corrosion protection by organic coatings:
electrochemical mechanism and novel methods of
investigation. Electrochimica Acta, 2000, 45(15-
16): 2515-2533
SVP-(Scanning Vibrating
Probe)

,
,

SRETScanning Reference
Electrode Technique

SVETScanning Vibrating
Electrode Technique (
SVET
SRET
SVP-

SVP


SVP

(
)
(SVP)
5A/cm2

Scanning vibrating reference electrode technique: a calibration study to

evaluate the optimum operating parameters for maximum signal detection of
point source activity
SKP-

SKP

SKP



SKP-
sample
= Work Function
E = Fermi Level probe

Vc
Metal Probe

EProbe ESample

Metal Sample
SKP-
= Work Function
E = Fermi Level

Metal Probe

EProbe = ESample

- - -
+++

Metal Sample
SKP-
Vb

Metal Probe

EProbe ESample
Vb = -Vc

Metal Sample
SKP-

Iac= 0 when Vb = -Vc

Iac Vb

Lock-in
Amplifier
30 m
Iac
EProbe ESample

Metal Sample
SVET-SKP

1.
2.


3.
4. 10-12A~10-15A

5. In-situ

6. 3D
SVP-SKP

/






SVP-SKP

(filiform corrosion)
L-B
-






 Steel Alloy
Weldment in Tap
0 hours
Water 3.5 hours

1 hour 48 hours

1.5 hours
51 hours
316L in H2SO4
300
C

200

Potential vs SCE (volts)

B
100
D

A 0
E
C
-100

A
-200
-5 -4 -3 -2 -1
2
Log I (Amps/cm )

B D

E
Correlation of to Ecorr

Simultaneous
measurement
of Wf and Ecorr

S. Yee, R.A.
Oriani and M.
Stratmann,
JECS 138 (1991)
Clear difference between non-
galvanized steel and galvanized
portion;

Overcoating of polymer does

not affect measurement of
underlying surface.
Chromate conversion coating, primer and topcoat

538.8m

459.3m

379.8m

Work Function (d ev)

300.2m

220.7m

141.1m

61.6m

-18.0m

-97.5m

-177.1m
-0.209 -256.6m
0 4K 8K 12K 16K 20K 24K 28K 32K 36K 40K
Displacement (m)

200

Corrosion potential (mv Vs. SHE)

Work function of exposed metal 0
Copper
-200
within scribe closely correlates Iron
-400
with Ecorr of Cr3+ (-0.744mV)
-600
using calibration curve; -800
Aluminum r = 0.9847258049
-1000
-800 -600 -400 -200 0 200 400 600 800 1000

Work function (mV Vs Fe)



400

200

-200
WF (meV)

-400

-600

-800
10
-1000
8
-1200 6
mm

0 2 4
4 6 8 10 2
mm 12 14 16 0

Au

-Gold / Au


8.1
Tafel




8.2


8.3


Kelvin/