• It also known as nuclear decay is the process by
which an unstable atomic nucleus loses energy (in terms of mass in its rest frame) by emitting radiation,. • such as an alpha particle, beta particle • A material containing such unstable nuclei is considered radioactive. • Certain highly excited short-lived nuclear states can decay through neutron emission, or more rarely, proton emission. • Radioactive decay is a stochastic (i.e. random) process at the level of single atoms, in that, according to quantum theory. • it is impossible to predict when a particular atom will decay, regardless of how long the atom has existed. • collection of atoms, the collection's expected decay rate is characterized in terms of their measured decay constants or half-lives. • This is the basis of radiometric dating. • The half-lives of radioactive atoms have no known upper limit, spanning a time range of over 55 orders of magnitude, from nearly instantaneous to far longer than the age of the universe. • The law states that small amount of disintegration of the isotope in a small period is directly proportional to the total number of radioactive nuclei and proportional constant. • What is radiation? • A radioactive atom is one that spontaneously emits energetic particles or waves (known as radiation). • This radiation is emitted when an unstable (i.e. radioactive) nucleus transforms to some other nucleus or energy level Types of Nuclear Radiation
• There are several types of particles or waves that may
shoot out of a radioactive nucleus. • Alpha particles, beta particles, gamma rays, and neutrons are the most common forms of ionizing (i.e. dangerous) radiation. • Alpha Particles • Named alpha because they were the first to be discovered, these particles are made up of 2 protons and 2 neutrons: the helium nucleus. • Often, large atoms decay by emitting an energetic alpha particle. • These particles are relatively large and positively charged, and therefore do not penetrate through matter very well. • A thin piece of paper can stop almost any alpha particle. • However, the particles cause extreme damage of materials that they stop in by displacing atoms as they slow. • Paper under sustained alpha-irradiation would degrade. • Beta Particles • Beta particles are energetic electrons that are emitted from the nucleus. • They are born when a neutron decays to a proton. • Since neutrons are neutral particles and protons are positive, conservation of charge requires a negatively charged electron to be emitted. • Some isotopes decay by converting a proton to a neutron, thus emitting a positron (an anti-electron). • These particles can penetrate matter more than can alpha particles, and it takes a small aluminum plate to stop most beta particles. • Gamma rays • Gamma rays are photons that are emitted from the nucleus. • Often an atom in an excited state will de-excite by emitting a gamma ray. • Gamma rays are similar to light waves and x-rays, except they are usually much higher frequency and consequently, more energetic. • This radiation has no charge, and can penetrate most matter easily, requiring lead bricks for shielding. Uranium Enrichment
• Uranium found in nature consists largely of two
isotopes, U-235 and U-238. • The production of energy in nuclear reactors is from the 'fission' or splitting of the U-235 atoms, a process which releases energy in the form of heat. • U-235 is the main fissile isotope of uranium. • Natural uranium contains 0.7% of the U-235 isotope. • The remaining 99.3% is mostly the U-238 isotope which does not contribute directly to the fission process (though it does so indirectly by the formation of fissile isotopes of plutonium). • Isotope separation is a physical process to concentrate (‘enrich’) one isotope relative to others. • Most reactors are light water reactors (of two types PWR and BWR) and require uranium to be enriched from 0.7% to 3-5% U-235 in their fuel. • This is normal low-enriched uranium (LEU). • There is some interest in taking enrichment levels to about 7%, and even close to 20% for certain special power reactor fuels, as high-assay LEU (HALEU). • Uranium-235 and U-238 are chemically identical, but differ in their physical properties, notably their mass. • The nucleus of the U-235 atom contains 92 protons and 143 neutrons, giving an atomic mass of 235 units. • The U-238 nucleus also has 92 protons but has 146 neutrons – three more than U-235 – and therefore has a mass of 238 units • The difference in mass between U-235 and U-238 allows the isotopes to be separated and makes it possible to increase or "enrich" the percentage of U-235. • All present and historic enrichment processes, directly or indirectly, make use of this small mass difference Gaseous Diffusion
• The gaseous diffusion process uses molecular
diffusion to separate a gas from a two-gas mixture. • The isotopic separation is accomplished by diffusing uranium [which has been combined with fluorine to form uranium hexafluoride (UF6) gas]. • through a porous membrane (barrier), and using the different molecular velocities of the two isotopes to achieve separation. • Gaseous diffusion was the first commercial process used in the United States to enrich uranium. • Process • In a gaseous diffusion enrichment plant, uranium hexafluoride (UF6) gas was fed into the plant's pipelines where it was pumped through special filters called barriers or porous membranes. • The holes in the barriers were so small that there was barely enough room for the UF6 gas molecules to pass through as shown in this . • The isotope enrichment occurred because the lighter UF6 gas molecules (with the U234 and U235 atoms) diffused faster through the barriers than the heavier UF6 gas molecules containing U238. • One barrier wasn't enough though. It took many hundreds of barriers, one after the other, before the UF6 gas contained enough U235 to be used in nuclear fuel. • At the end of the process, the enriched UF6 gas was withdrawn from the pipelines and condensed back into a liquid that was then poured into containers. • The UF6 was allowed to cool and solidify before it was transported to fuel fabrication facilities. • The diagram to the right illustrates the gaseous diffusion enrichment process. • Gas Centrifuge • Gas centrifuge enrichment is the current process by which commercial enrichment is being performed in the United States. • UF6 gas is placed in a gas centrifuge cylinder and rotated at a high speed. • This rotation creates a strong centrifugal force so that the heavier gas molecules (UF6 containing U238 atoms) move towards the outside of the cylinder. • The lighter gas molecules (containing U235) collect closer to the center. • The stream that is slightly enriched in U235 is withdrawn and fed into the next centrifuge; the next higher stage. • The slightly depleted stream (with a lower concentration of U235) is recycled back into the next lower stage. • A gas centrifuge facility contains long lines of many rotating cylinders. • These cylinders are connected in both series and parallel formations. • Centrifuge machines are interconnected to form trains and cascades. • At the final withdrawal point, the UF6 is enriched to the desired amount. BWR PWR Power Reactors
• The commercial nuclear power plants that generate
electricity. • There are several types of these power reactors. Of these, only the Pressurized Water Reactors (PWRs) and Boiling Water Reactors (BWRs) are in commercial operation . • Select a type from the list below to view a description and diagram of each. • Pressurized Water Reactors (PWRs) • Boiling Water Reactors (BWRs) Pressurized-Water Reactor • How Nuclear Reactors Work • In a typical design concept of a commercial PWR, the following process occurs: • The core inside the reactor vessel creates heat. • Pressurized water in the primary coolant loop carries the heat to the steam generator. • Inside the steam generator, heat from the primary coolant loop vaporizes the water in a secondary loop, producing steam. • The steamline directs the steam to the main turbine, causing it to turn the turbine generator, which produces electricity. • The unused steam is exhausted to the condenser, where it is condensed into water. • The resulting water is pumped out of the condenser with a series of pumps, reheated, and pumped back to the steam generator. • The reactor's core contains fuel assemblies that are cooled by water circulated using electrically powered pumps. • These pumps and other operating systems in the plant receive their power from the electrical grid. • If offsite power is lost, emergency cooling water is supplied by other pumps, which can be powered by onsite diesel generators. • Other safety systems, such as the containment cooling system, also need electric power. • PWRs contain between 150-200 fuel assemblies Boiling-Water Reactor • How Nuclear Reactors Work • In a typical design concept of a commercial BWR, the following process occurs: • The core inside the reactor vessel creates heat. • A steam-water mixture is produced when very pure water (reactor coolant) moves upward through the core, absorbing heat. • The steam-water mixture leaves the top of the core and enters the two stages of moisture separation where water droplets are removed before the steam is allowed to enter the steamline. • The steamline directs the steam to the main turbine, causing it to turn the turbine generator, which produces electricity. • The unused steam is exhausted to the condenser, where it is condensed into water. The resulting water is pumped out of the condenser with a series of pumps, reheated, and pumped back to the reactor vessel. • The reactor's core contains fuel assemblies that are cooled by water circulated using electrically powered pumps. • These pumps and other operating systems in the plant receive their power from the electrical grid. • If offsite power is lost, emergency cooling water is supplied by other pumps, which can be powered by onsite diesel generators. • Other safety systems, such as the containment cooling system, also need electric power. BWRs contain between 370-800 fuel assemblies. • Fission Reaction?