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Objective
To determine the higher heating
value (total calorific value, or gross
heat of combustion) and the lower
heating value of a sample of liquid
diesel fuel using a non-adiabatic
bomb calorimeter
What is a Bomb Calorimeter?
A device used to measure the heating value of a liquid
or solid fuel
Uses the same principle of a gas calorimeter, but
operates at constant volume
Uses pure oxygen instead of air
Two distinct types:
Adiabatic (No heat transfer with the surrounding)
Non-adiabatic (Some heat can be transferred between
the calorimeter and the surrounding environment)
Figure 1- A Parr plain Bomb calorimeter
How Does it Work?
Sample fuel is burned with pure oxygen in a
pressurized constant volume combustion chamber
(bomb)
Heat of combustion is transferred to the water in the
inner jacket (bucket)
Temperature change of water is measured
Knowing the mass and specific heat of water and
bomb, the amount of transferred heat is measured
Appropriate corrections are applied to find the higher
heating value
Figure 2-Cross section of a plain calorimeter
Main components:
A. Thermometer
B. Inner jacket (Bucket)
C. Bomb
D. Stirrer
E. Stirrer motor
F. Wire to firing
mechanism
Higher Heating Value
The heat absorbed by the bomb and water
equals to :
Q=W∆𝑻
Where:
W=(𝒎𝑪)𝒃𝒐𝒎𝒃 +(𝒎𝒄)𝒘𝒂𝒕𝒆𝒓
W is called the bomb calorimeter water equivalent
∆𝑻 = (𝑻𝒇𝒊𝒏𝒂𝒍 − 𝑻𝒊𝒏𝒊𝒕𝒊𝒂𝒍 )
Major Corrections Applied:
Radiation Correction (only for non-adiabatic
calorimeter)
Acid Corrections (𝑒1 & 𝑒2 )
Fuse wire correction (𝑒3 )
Correction to account for combustion happening at
constant volume instead of constant pressure (𝑒4 )
Correction to account for the combustion products not
being at the same temperature as the reactants (𝑒5 )
Radiation Correction
In a non-adiabatic bomb calorimeter some heat is
exchanged between the water in the bucket and the main
jacket, therefore ,∆𝑇 must be corrected
To find the corrected temperature change, from collected
data:
Temperature vs. time is plotted
𝑇𝑖 (initial Temperature), 𝑇𝑎 (ignition Temperature),
𝑇𝑐 (maximumTemperature), and 𝑇𝑓 (final Temperature) are
marked on the graph
𝑇𝑏 (the temperature at which 60% of temperature change
occurs),𝑟1 𝑎𝑛𝑑 𝑟2 (rate of heat transfer prior to ignition and
after maximum T is reached) are calculated
FIG. 3: An example of (temperature, time) data plot showing the
positions for reading Ti, Ta, Tb, Tc, and Tf
Corrected Temperature change
𝑇𝑏 = 𝑇𝑎 + 0.6(𝑇𝑐 − 𝑇𝑎 )
𝑇𝑎 − 𝑇𝑖
𝑟1 =
𝑡𝑎 − 𝑡𝑖
𝑇𝑐 − 𝑇𝑓
𝑟2 =
𝑡𝑓 − 𝑡𝑐
Where: T stands for temperature and t stands for time
Where:
W=1346 cal/ 𝑜𝐹 = 2423 𝑐𝑎𝑙/ 𝑜𝐶
𝑚𝑓𝑢𝑒𝑙 = 1 gram
𝑒4 = - 23 Cal/gram of fuel
𝑒5 = 3.94 cal/ 𝑜𝐶 × (𝑇𝑓 − 𝑇𝑖 )
(𝑇𝑓 − 𝑇𝑖 ) must be in 𝑜𝐶
Lower Heating Value
LHV = HHV -𝒎𝒘𝒂𝒕𝒆𝒓 𝒉𝒇𝒈,𝒘𝒂𝒕𝒆𝒓 𝒂𝒕 𝟐𝟓 𝒐𝑪
𝟏×𝟏.𝟎𝟓×𝟏𝟖 𝒈𝒘𝒂𝒕𝒆𝒓
𝒎𝒘𝒂𝒕𝒆𝒓 = = 1.34
𝟏𝟒.𝟏 𝒈𝒇𝒖𝒆𝒍
𝑘𝐽 𝑐𝑎𝑙
𝒉𝒇𝒈,𝒘𝒂𝒕𝒆𝒓 𝒂𝒕 𝟐𝟓 𝒐𝑪 =2441.7 = 583.19
𝑘𝑔 𝑔