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TYPES OF CO2REMOVAL
PROCESS
1.Chemical WASHING
2.PHYSICAL WASHING
3.SOLID ADSORPTION:
PRESSURE SWING ADSORPTION
CO2 REMOVAL
DIFF.PROCESSES
1.Chemical-potassium carbonate system :
Benfield,
Giammarco-vetrocoke(GV)
Catacarb
- Alkanolamine systems: MDEA
2.Non chemical- Selexol
Fluor solvent
BASF Sepasolv
Rectisol
CO2 REMOVAL:potassium
carbonate systems
1270c LS
LS 1160c
Cond. 1220c
Activator: Glycin e with DEA
Benfield Process
Activator : Diethanolamine(DEA)
Hydraulic
carbonate turbine
reboiler
condensate
reboiler 930C
28.3KG/CM2
LP
condensate 1300C 1220C 1120C
reboiler
BFW lean soln. Semilean soln.
heater pump pump
Acid gas
Lean soln.
Feed Gas regenerator cooler
absorber
condensate
reboiler Hydraulic
turbine
carbonate
reboiler 4-stage flash tank Benfield
and ejectors soln. pump
BFW
heater
Catacarb process
Activator : Amine borate
430c 1. 38 bara
CO2
CW
Semilean
DISCHARGES Treated gas
regenerator
PROCESS 840 c
Lean
GAS 310 t/h
Regenerator 850 c
1960c absorber
reboiler 2050 t/h
SC 1200c
29 . 5 bara
1250c
3 . 5 barg 1260c
610c
Reboiler steam
1000c
1000c
740C stripper
Feed gas
700C
830C 1120C
absorber hp flash
lean/semi-lean exchanger
aMDEA: 40% MDEA and 6.5% Piprazine.
Density: 80 % of K2CO3
External reboil duty : 40 MJ/kmol
BASF’s a MDEA
PROCESS
Advantages
Non-corrosive solvent
No toxic corrosion inhivitors
No passivation procedure
Lower thermal energy consumption
No solid precipitation
No special heat tracing
High thermal and chemical stability of the
solvent,therefore no degradation.
Low vapor pressure, therefore low solvent loss.
It is environment friendly and biodegradable
chemical.
BASF’s a MDEA
PROCESS
Process Description of Two stage a-MDEA.
The solvent is an Amine solution, Methyl-di-ethanol amine
(MDEA) being the active component. In addition, the scrubbing
solution contains an activator (Piprazine) to enhance the CO2
absorption rate.
The feed gas enters the absorber at the bottom, and CO2 is
removed from the gas by counter-current absorption in two
stages. In the bottom portion of the absorber,flash regenerated
solution is used for bulk CO2 removal. In the top portion of the
absorber, stripped solvent is used for purification to
specification. The treated gas with a CO2 conc. Of less than 50
ppm, leaves the absorber.
BASF’s a MDEA
PROCESS
Co2 absorber
Co2 slip
CO2
Semi-lean
1000 PPM
STRIPPER
Cooler Lean/rich
500 PPM
New LEAN
exchanger(New)
Reboiler
RICH
54MW
29MW
External reboil duty reduced from 120 MJ/ kmol to 65 MJ/kmol
CO2 REMOVAL:Corrosion
Inhibitor
Reduce maintenance .
CO2 REMOVAL:Corrosion
Inhibitor
A.Types of antifoam
- Polyglycols ( UCON, NIXOLEN SL 150 etc.)
- Silicones
-High M.W. Alcohol
B. Causes of foaming Due to Contamination
-Particulate
dirt, rust, sooth, catalyst dust, etc.
-Hydrocarbons
oils & greases
-Plasticizers
DEA degradation compounds
CO2 REMOVAL:Foaming
Indications of foaming:
s
Lean soln. Oxid.soln.
from To soln.
lean soln. Storage
pump tank
CW Instrument air
CO2 REMOVAL:Filtration
Mechanical Filters
5 micron filter elements to catch suspended particles, rust, catalyst dust,
refractory etc.
Carbon Filter
Activated carbon to filter out foaming impurities.
To & from
aeration system
Disadvantage:
•Volatility is a prime concern in choice of solvent
•Physical solvents have slow absorption, so larger vessels required and circulation
of solvent is high.
•In process gas CO2 slip is high for ammonia plant requirement.
.
CO2 REMOVAL
Physical absorption.
Selexol process -Here solvent used is a
homologue of diethylether of polyethylene-
glycols.
Rectisol process - The method uses
various organic liquids as solvent, but for
ammonia syn. Gas, methanol is choice.The
process is quite flexible in regard to
operating pressure and composition of
feed gas.
CO2 REMOVAL:Solid
Adsorption
1160c