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2 CONFIDENTIAL
Difference between Flooded and AGM’s
η = a ± b log(I)
4 CONFIDENTIAL
Polarization vs. Current
Charge
OCV
Polarization
Battery on-float
Low-rate discharge
Higher-rate discharge
Discharge
Current
Difference between Flooded and AGM’s
Flooded
• Liquid electrolyte
• Evolved gases escape to
atmosphere
• Separate battery room required with
ventillation system for dispersal of
hydrogen
• Can be topped up with water
• Can only be operated upright
• Spill containment
system is required
Difference between Flooded and AGM’s
AGM’s
• Electrolyte absorbed in
glass mat
• No spill containment
required
• Evolved gases recombine
and stay within the battery
• No need to top up with
water
• Can be operated in any
orientation
Difference between Flooded and AGM’s
Mass Balance - Flooded
Excess
• Flooded LA’s have an excess of electrolyte
• Easier to over discharge the positive electrode
• Higher heat capacity, 30-40% since there is relatively more
liquid…
Difference between Flooded and AGM’s
Mass Balance - AGM
PbO2 + Pb + 2H2SO4 2 PbSO4 + 2H2O
Excess Limited
13 CONFIDENTIAL
Why Are VRLAs So Finicky? (cont’d)
14 CONFIDENTIAL
VRLAs Are Several Distinct Designs
• Gel Cells
• Typically require a lower charge voltage.
• If charged at too high a rate, gel cells tend to
form bubbles within the gel electrolyte which
can cause permanent damage.
• Typical recommendation is maximum of 2.3 to
2.35 VPC @ 10% of rated ampacity.
• If charged at these voltage levels, charge voltage
must be reduced to recommended float voltage
as full charge level is reached.
15 CONFIDENTIAL
VRLAs Are Several Distinct Designs
16 CONFIDENTIAL
VRLAs Are Several Distinct Designs
• Pure Lead
• Typical maximum recommended charge
voltage is 2.45 to 2.65 VPC, with some
manufacturers specifying C/5 and higher CC
charge rates.
• Temperature compensated charging is highly
recommended.
17 CONFIDENTIAL
VRLA Caveats
18 CONFIDENTIAL
Additional VRLA Topics
• Charging Parallel Strings
• Battery Monitoring
• Equalize Charging
19 CONFIDENTIAL