Professional Documents
Culture Documents
By
Dr Anil Kumar
Fluid Properties
Naturally occurring petroleum accumulations are made up of
large number of organic compounds, primarily hydrocarbons.
Seldom are two crude oil samples identical and seldom are two
crude oils made up of the same proportions of the various
compounds.
Reasons to examine the Reservoir fluids
a) A chemical engineer may be interested in a crude oil’s
composition as to the amount of commercial products the
oil will yield after refining.
b) An exploration might have an interest in an oil or water’s
composition as it sheds light on the origin, maturation and
degradation of the oil for geological interpretation.
c) The petroleum engineer is particularly concerned to
determine their behavior under varying conditions of
pressure and temperature that occur in the reservoir and
piping systems during the production process.
Chemical composition of petroleum deposits
2. Naphthalene hydrocarbons
3. Aromatic hydrocarbons
Petroleum oil
Kerosene 400-575 0f
Fuel oil Above 575 0f
Requirements to Study the Reservoir Fluid Behavior
The vapor pressure and bubble point lines do not coincide but
form an envelope enclosing a broad range of temperatures and
pressures at which two phases (gas and oil) exist in equilibrium.
Oil reservoirs
If the reservoir temperature T is less than the critical
temperature Tc of the reservoir fluid, the reservoir is
classified as an oil reservoir.
Gas reservoirs
If the reservoir temperature is greater than the critical
temperature of the hydrocarbon fluid, the reservoir is
considered a gas reservoir.
P-T Diagram for a Multicomponent
Reservoir Fluid Types
3. Gas-cap reservoir.
If the initial reservoir pressure is below the
bubble point pressure of the reservoir fluid, the
reservoir is termed a gas-cap or two-phase
reservoir, in which the gas or vapor phase is
underlain by an oil phase. The appropriate
quality line gives the ratio of the gas-cap volume
to reservoir oil volume.
Reservoir Fluid Types
• Black oil
• Volatile oil
Pres , Tres
• Retrograde Condensate Dry
(gas condensate)
Pressure
Gas
Gas
• Wet gas Condensate
Volatile Black
• Dry gas Oil Oil
Temperature
Reservoir Fluid Types
• Oil formation
volume factor less
than 1.2 bbl/STB
• Gas-oil ratio less
than 200 scf/STB
• Oil gravity less than
35° API
• Black or deeply
coloured.
• Substantial liquid
recovery at
separator condition.
P-T Diagram for a Volatile Oil
Volatile Oil
The near-critical
crude oil is
characterized
by a high GOR in
excess of 3,000
scf/STB.
Oil formation volume
factor of 2.0 bbl/STB
or higher.
P-T Diagram for gas condensate
P-T Diagram for gas condensate
• Oil Compressibility
• Saturation Pressure
• Live Oil Viscosity
• Live Oil Density
• Oil Formation Volume Factor
• Gas-Oil Ratio
1. Liberated GOR
2. Solution GOR
• Liberated Gas Formation Volume factor
• Incremental Liberated Gas-Gravity
• Cumulative liberated Gas-Gravity
Reservoir Fluid Properties
Oil Compressibility
The compressibility of any substance is the change in volume
per unit volume for per unit change in pressure. By
definition, the isothermal compressibility of a substance is
defined mathematically by the following expression:
Saturation Pressure
The pressure at which oil is saturated with gas and it can
not further dissolve gas is called saturation pressure
Reservoir Fluid Properties
Gas-Oil Ratio
The gas/oil ratio (GOR) is the ratio of the volume of gas
that comes out of solution, to the volume of oil at
standard conditions.
1. Liberated GOR
2. Solution GOR
Liberated Gas Formation Volume factor
The gas formation volume factor, Bg, is defined as the
ratio of the volume of gas at the prevailing reservoir
temperature and pressure to the volume of gas at
standard conditions.
Reservoir Fluid Sampling
Sampling of Reservoir Fluids
• The purpose of sampling is to obtain a representative
sample of reservoir fluid identical to the initial reservoir
fluid.
Downhole
DST strings
Wireline sample
Surface
Wellhead samples
Separator samples
Sub-surface sampling for Oil Reservoirs
momentum Gauge
absorber
Inlet Gas
Outlet
Sight Liquid
Glass Outlet
Recombination of surface Sample
Isothermal Flash
Vapour
Vapour
Black Volatile
Oil Oil
Volume
Volume
Pb Pressure Pb Pressure
Constant Volume Depletion (CVD)
Vapour
Vapour
Vapour Vapour
Vapour
Vapour Vapour
Psat P1 P1 P2 P2
Differential Vaporisation (DV)
A series of flash expansions at T
At each pressure stage, all of the vapour
in the cell is removed
Vapour
Vapour
Vapour Vapour
Psat P1 P1 P2 P2
The liquid remaining at the last pressure step is cooled to ambient
temperature to give the residual oil
DV Reported Data
Oil volume
Oil density
Oil formation volume factor, Bo
Gas specific gravity
Gas Z-factor
Gas formation volume factor, Bg
Evolved gas volumes
Solution GOR, Rs
Example
Results of Differential Liberation
Pressure Two phase Single phase Gas Vol at
Psia Volume Volume surface
Cc at 150 0F cc cc
2000 20
1800 (BP) 20.9
1400 24 19 595
1000 25 18.1 585
600 26.8 16.9 590
300 30 15.7 580
atm 14.65 650