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McMurry
www.cengage.com/chemistry/mcmurry
Chapter 13
Structure Determination:
Nuclear Magnetic
Resonance Spectroscopy
molecules
Shielding: Opposing magnetic field produced
by electrons surrounding nuclei to counteract
the effects of an external magnetic field
Effect on the nucleus is lesser than the applied
magnetic field
Beffective = Bapplied – Blocal
Individual variances in the electronic environment
of nuclei leads to different shielding intensities
1454Hz
δ= = 7.27 δ for CHCl3
200MHz