Professional Documents
Culture Documents
Booms
10-22-09
Acetylene bottle
stored in plumbers
van
Gas ignited by
1. Legislation
2. Safety Advisers
3. Duties of participants
4. Driver training
5. Documentation
6. Packaging
7. Vehicle equipment and marking
8. Quantity exemptions and Limited Quantity
9. Examples – how much can I carry with exemptions?
10. General exemptions and questions
Who wants to take the next load of TDG without
Training
Transportation of Dangerous Goods
(TDG)
Overview of TDG Regulations
Classification of Dangerous Goods
Safety Marks & Placards
Empty Containers & Vehicles
Emergency Response
Documentation
Definition Under the Law
“Dangerous goods” means any product,
substance, or organism included by its nature
or by the regulations in any of the classes
listed in the schedule.”
“The Schedule” referred to above is Schedule
II of the Transportation of Dangerous Goods
Regulations.
Objectives
To promote public safety during handling and
transport
Different from WHMIS which focuses on
employee health & safety
Prohibits anyone from transporting dangerous
goods unless it is with the requirements of the
Act and TDG Regulations.
TDG Regulations, Section 9.7
No person shall handle, offer for transport,
or transport dangerous goods unless they
are:
Trained in aspects of the TDG Regulations, and
issued a Certificate of Training, or
Under the direct supervision of a trained person.
Training Certificate is valid for 3 years.
Handling
means loading, packing or placing, unloading, unpacking or
removing, or reloading, repackaging or replacing dangerous
goods in or from any container, packaging, or means of
transport or at any facility for the purposes of, in the course of
or following transportation and includes storing dangerous
goods in the course of transportation of dangerous goods.
Safety Mark
includes any design, symbol, device, sign, label, placard,
letter, word, number, abbreviation or any combination thereof
that is to be displayed on dangerous goods or containers,
packaging, means of transport or facilities used in the
handling, offering for transport or transporting of dangerous
goods.
Continued ...
Shipping Document
means any document that accompanies dangerous goods
being handling, offered for transport or transported and that
describes or contains information relating to the goods, and
in particular, but without restricting the generality of the
foregoing, includes a bill of lading, cargo manifest, shipping
order, way-bill, and switching order.
Packing Group
indicates the degree of danger within a given classification
of dangerous goods. Group I, great danger; Group II
moderate danger; Group III, minor danger.
Nine Classes Based on Hazard Type
Class 1: Explosives
Class 2: Gases
Class 3: Flammable Liquids
Class 4: Flammable Solids
Class 5: Oxidizers
Class 6: Poisons
Class 7: Radioactive Materials
Class 8: Corrosives
Class 9: Miscellaneous
Step 1: Determine if material is exempt
Refer to Part II (Section 2.3) of TDG
Regulations to determine if exempt. If so,
classification is not required.
Step 2: Determine Classification
Refer to Schedule II of TDG Regulations.
List I consists of explosive materials.
List II consists of more than 3000 dangerous
goods, other than explosives.
Gasoline & Diesel Fuel
TDGR Section 2.31 makes partial
exemptions for transportation by road if:
Containers are transported in open vehicle so
label or placard is visible from outside the
vehicle;
Each container is secured to the vehicle
during transport; and
Total capacity of containers in/on vehicle is
not more than 2,000 liters.
Continued ...
Propane
TDGR Section 2.31makes partial exemptions
for transportation by road if:
Containers are transported in open vehicle so
label or placard is visible from outside the
vehicle;
Each cylinder is secured to the vehicle during
transport; and
Total quantity being transported is not greater
than 500 kg.
Herbicides & Pesticides
TDGR Section 2.31makes partial exemptions
for transportation by road if:
The product or solution is transported in a tank
having a volume of 5000 L or less.;
Tank is being used for mixing or holding of
product prior to or during application
procedures;
Tank is properly placarded
Gasoline, Diesel Fuel, & Propane
Exempt from:
Using TDG shipping document
Using placards on vehicles (except
herbicides/pesticides)
Training, registration, reporting
Not exempt from:
Immediately notifying authorities if
dangerous goods are lost or released.
Filing written report for spills/releases.
Labeling containers.
Herbicides & Pesticides
Exempt from:
Using TDG shipping document
Training, registration, reporting
Not exempt from:
Immediately notifying authorities if
dangerous goods are lost or released.
Filing written report for spills/releases.
Labeling containers.
Division 2.1 - Flammable
Gases
Propane, acetylene
Division 2.2 - Non-
Flammable Gases
Refrigerant, nitrogen,
oxygen
Division 2.3 - Poisonous
Gas
Carbon dioxide, sulfur
dioxide
Hazards
Explosion or fire
Container rupture
Container rocketing
Frostbite
Asphyxiation
Toxicity
Irritation
Liquids with a flash point < 61deg C
Commonly used as fuels
Gasoline, fuel oil, diesel
Flash Point
Minimum temperature at which a liquid gives
off sufficient vapour to form an ignitable
mixture with air at the surface of the liquid.
Hazards
Fire
Explosions
Toxic fumes
Corrosivity
Water contamination
Poisonous or Infectious
Materials
A solid or liquid that is poisonous
by inhalation of vapours, by skin
contact or by ingestion.
Examples: pesticides, lead
compounds, disinfectants, some
solvents, hospital wastes.
6
Types
Labels: used for packages, cylinders, small
containers
Placards: used for large containers, trucks,
other transport units
Signs: special placards such as “Danger”
Other Marks: additional information (e.g.,
shipping name, PIN, container orientation,
etc. on smaller containers).
Mandatory Use
Safety marks used to indicate:
Presence of dangerous goods
Type and degree of associated risk
Safety marks must be used on all containers,
packages, tanks, cylinders and transport units
used for transporting dangerous goods.
Special Placards
If the quantities of individual
D A N G E R
classes do not exceed the small
quantity limit, but the total
quantity of dangerous goods
exceeds 454 kg, the a “danger”
placard must be displayed on the
vehicle.
Segregation of Incompatible Materials
TDGR have requirements and prohibitions
for transporting incompatible materials
(see Compatibility Chart) on the same
vehicle.
Examples:
Liquid fuels may be transported with propane
Propane & herbicides can only be transported
together if separated such that leakage will
not impact the other material
Liquid fuels must not be transported with
herbicides/pesticides
Special segregated storage is required for the following Dangerous Goods Classes:
Prescribed substances' under the Dangerous Goods Code are assigned a specific United
Nations "UN" number and are divided into the following nine classes according to their
predominant hazard:
Class 1 - Explosives
Class 2 - Gases (flammable, non-flammable, toxic)
Class 3 - Flammable liquids
Class 4 - Flammable solids, solids liable to spontaneous combustion,
and substances that emit flammable gases when wet
Class 5 - Oxidising substances (oxidising agents and organic peroxides)
Class 6 - Toxic and infectious substances
Class 7 - Radioactive material
Class 8 - Corrosive substances
Class 9 - Miscellaneous dangerous substances
Subsidiary Risk - dangerous goods that pose more than the risk that is denoted by
their class.
Storage Considerations – what goes with what?
Each class is identified by a distinctive coloured, diamond shaped label
A discharge, emission or escape from any
container must be reported if:
Greater than “quantity for immediate
reporting”
Class 2.1 (Propane): 100L
Class 3 (Gasoline, Diesel): 200L
Class 6: (Herbicide, Pesticides): 5kg / 5L
All fires and explosions involving
dangerous goods must be reported.
Immediate Notification
A person who has charge of dangerous
goods and discovers or is advised of a spill,
release or fire shall immediately notify:
Local police
His/her employer
Owner, lessee of vehicle
Owner or consignor or shipment
Written Report
Employer must complete Form 2 within 30
days and forward it to Transport Canada.
Class 1 - Explosives
Pratt Safety
Class 3 is divided in the following way for packing/transport:
Flammables Cabinet
Class 3 Packing Group I is Boiling Point <=35°C.
model 5560 AS
Class 3 Packing Group II is Flash Point <=23°C, Boiling Point > 35°C.
Class 3 Packing Group III is Flash Point > 23°C to <=61°C, Boiling Point
>35°C.
Class 4 - Flammable Solids
Solid substances which are flammable in air and can sustain
spontaneous combustion and emit flammable gases upon contact with
water.
CLASS 5 STORAGE:
Separate from all other classes in a designated
cupboard, particularly from Classes 3, 4, and 8
Lockable
Cement sheet lined (eg “Hardiflex”)
Signed (“Class 5: Oxidising Agents”)
Class 6
ClassToxic and
6.1 – Toxic infectious
substances substances
likely to cause death or severe
injury to human or animal health if swallowed, inhaled or by skin
contact.
N)
Gases ether, pentane
GE
Oxygen, Solids
FU
fluorine, plastics, wood
XY
chlorine dust, fibers, metal
EL
hydrogen (O particles
peroxide, nitric
R
acid, perchloric
Gases
AI
76
Liquid pool formation
A liquid pool forms – pool formation model.
77
Pool fire
There is a probability (e.g. 30%) of ignition.
78
Pool fire
As the pool fire develops the other compartments are
79
Explosion (BLEVE)
Pressure builds up while the container walls weaken
because of the intense heat. This may result
(depending on the amount of leakage and prevailing
conditions) in a “boiling liquid expanding vapour
explosion” (BLEVE).
(Associated probability and consequence modeling)
80
Flash Point
Lowest temperature at which a
flammable liquid gives off enough
vapor to form an ignitable mixture
with air
E
AUTO
R
SU
IGNITION
ES FLAMMABLE
FLAMMABLE REGION
PR
MIST
REGION
R
PO
VA
LOWER LIM
IT
TEMPERATURE AIT
FLASH
POINT
Limiting O2
LOC Concentration:
Vol. % O2 below
which
1 Atmosphere combustion can’t
25°C occur
FLAMMABLE
HE
MIXTURES
L
LEL
Hazard: the property of a
substance or situation with the
potential for creating damage
Risk assessment is a
continuous process!
Risk Analysis
Likelihood Consequences
Risk
Interpretation of the
values
P r e s s u r e -
l i q u e f i e d G a s
I n s t a n t a n e o u s
T a n k R u p t u r e
I m m e d i a t e i g I nn si t t i ao nn t a n e o u s C l o u d /
B L E V E P o o l E v a p o r a t i o n
D i s p e r s i o n
N e a r m i s s I g n i t i o n a n d d e D t o e nl a a y t ie o d n I g n i t i o n
E x p lo s i o n F l a s h f i r e
P r e s s u r e -
l i q u e f i e d G a s
T w o - p h a s e j e t
N o i g n i t i o n I m m e d i a t e i g n i t i o
D i s p e r s i o n J e t F i r e
N o i g n i t i o n D e l a y e d I g nI g i tn i oi t ni o n a n d d e t o n
N e a r m i s s F l a s h f i r e E x p l o s i o n
Jet
High speed (high momentum), rapid mixing,
single direction
Dense (= denser than air) clouds:
Dense gas ”slumps” in all directions (even
against the wind)
Dense clouds are shallow
Density layering (stratification) reduces mixing
Buoyant (= lighter than air)plume
plume rise
Dispatch 0230 hours for car fire (Engine
10)
E10 arrived and requested FIB for
multiple vehicles with possible structural
exposures (freeway columns and
overpasses)
12 vehicles damaged or destroyed
Firefighter near miss when CNG vehicle
exploded as E10 crew approached with a
handline (approximately 50-75’ away)
Determined to be arson
Fire
Garage
E10 parked outside
outsid
the gate here
Bumper frame
++
++
100’ Trunk lid
Backhoe
Fuel tank
Roof debris (original location)
Honda CNG Vehicle
Rear of vehicle
Roof is blown completely
off vehicle and doors blown
open
Metal mounting
straps for CNG tank
Trunk lid
Tank initially landed …then was moved down
here, about 100’ away the hill for extinguishmen
Evidence indicates it
may have ricocheted off
the underside of a
freeway overpass (next
picture).
90’
Rear bumper frame 90’+ away
Bumper shrapnel
(note burn marks on
ground)
Roof section about 75’ away
This may be your only warning of
a CNG – fueled vehicle. Typically
located on the trunk lid or bumpe
omposite tank is carbon-fiber / fiberglass
rapped for strength – similar to our SCBA tank
LEL / UEL = 4 – 16% (gasoline = 1.3 – 7.6)
1 cubic foot of CNG = 245 cu.ft. of natural
gas at sea level (uncompressed)
1 cubic foot of CNG weighs 13#
5.66# = 1 Gasoline Gallon Equivalent
(GGE)
Honda Civic tank = 8 GGE
Note: 1 gallon of gasoline properly
vaporized has the explosive equivalency of
83 pounds of dynamite (CDC).
Determine vehicle type during size-up
Use 45° approach angle
Watch for additional hazards
Consider cooling streams from a distance
If CNG vehicle, remember best practices:
#1 – KEYS
#2 – ELECTRICAL
#3 – GAS
Inerts
Temperature
Pressure
Source Percent of Accidents
Electrical 23
Smoking 18
Friction 10
Overheated Materials 8
Hot Surfaces 7
Burner Flames 7
…
Cutting, Welding, Mech. Sparks 6
…
Static Sparks 1
All Other 20
Fire
A slow form of deflagration
Deflagration
Propagating reactions in which the energy
transfer from the reaction zone to the unreacted
zone is accomplished thru ordinary transport
processes such as heat and mass transfer.
Detonation / Explosion
Propagating reactions in which energy is
transferred from the reaction zone to the
unreacted zone on a reactive shock wave. The
velocity of the shock wave always exceeds sonic
velocity in the reactant.
Stored Volumes of Ideal Gas at 20° C
PRESSURE, psig TNT EQUIV., lbs. per
ft3
10 0.001
100 0.02
1000 1.42
10000 6.53
Good weather
Stable atmospheres,
low wind speeds
Peak Equivalent
OverpressurWind Velocity Effects
e mph
psi
1 Knock personnel
2 70 down
5 160
10 290 Rupture eardrums
15
20 470 Damage lungs
30 670
35
50 940 Threshold fatalities
65 50% fatalities
99% fatalities
World of explosives is dominated by TNT
impact which is understood.
Vapor clouds, by analysis of incidents,
seem to respond like TNT if we can
determine the equivalent TNT.
1 pound of TNT has a LHV of 1890 BTU/lb.
1 pound of hydrocarbon has a LHV of
about 19000 BTU/lb.
A vapor cloud with a 10% efficiency will
respond like a similar weight of TNT.
INVENTORY UVCE BLEVE FIRE
(tons)
1 120 18 Distance
2 150 36 in Meters
5 200 60
10 250 90 20
20 310 13 30
50 420 0 36
100 530 20 50
200 670 0 60
500 900 28 100
1000 1150 0 130
40
0
60
Fire or Flames Typical Control
Spacing and Layout
Furnaces and Boilers
Spacing and Layout
Flares
Work Procedures
Welding Work Procedures
Sparks from Tools Sewer Design, Diking,
Spread from Other Areas Weed Control,
Housekeeping
Matches and Lighters Procedures
GROUNDING
BONDING
Several thousands of trucks carrying dangerous goods circulate
within Canadian roads on daily basis.
They utilise urban roads, rural roads, highways, tunnels and
long bridges and in some case they are not allowed in some of
them.
However the actual accident risk and impact is not calculated.
In addition, when, due to unforeseen events (traffic jams,
accidents, etc.), they need to change route, they do not have any
particular guidance on the safest alternative nor are
consequences of road choice to the business chain and societal
risk calculated.
137
Liquid Leakage
After an accident or a malfunction a flammable gas
leaks. (Associated probabilities for large and small
leaks)
138
Explosion (BLEVE)
Pressure builds up while the container walls weaken
because of the intense heat. This may result
(depending on the amount of leakage and prevailing
conditions) in a “boiling liquid expanding vapour
explosion” (BLEVE).
(Associated probability and consequence modeling)
139
The Individual Risk for a
point-location around the
dangerous goods
transportation activity is
defined as the probability
that an average
unprotected person
permanently present at
that point location, would
get killed due to an
accident during the
dangerous goods
transportation activity.
It is used to estimate the
risk of a hypothetical
“average” individual as a
function of distance from
the hazard. Individual
140
Class I Flammable gases/vapors present
National
Electrical Class II Combustible dusts present
Code (NEC)
Class III Combustible dusts present but not
defines area
likely in suspension
classification
s as a Group A Acetylene
function of Group B Hydrogen, ethylene
the nature
and degree Group C CO, H2S
of process Group D Butane, ethane
hazards
present Division 1 Flammable concentrations
normally present
Division 2 Flammable materials are normally
in closed systems
Anyone involved in the transportation of
regulated hazardous materials must be
trained
Packaging shipments
Preparing shipping papers
Receiving hazardous materials
CANUTEC (Canadian Transport Emergency Centre)
provides 24-hour-a-day bilingual emergency advisory and
regulatory information service. CANUTEC's experienced
professional chemists assist emergency responders in the
event of a dangerous goods accident.
It includes information on accident flows and trends,
regulatory interpretations, reports on national and
international events, regulatory and compliance
requirements and activities, risk management and
assessment techniques, emergency response and data
compilation and reports.