Professional Documents
Culture Documents
ON
DENTURE BASED RESINS
PRESENTED BY
BEENU V
1ST YEAR PG
CONTENTS
INTRODUCTION
IDEAL REQUIREMENTS
CLASSIFICATION
POLYMERIZATION REACTION
DIFFERENT TYPES OF DENTURE BASE RESINS
SEPERATING MEDIA
PROPERTIES OF DENTURE BASE RESIN
RECENT ADVANCES
SUMMARY
INTRODUCTION
The denture base is the part of denture which rests on the soft
tissue, so does not includes the artificial teeth.
Prior to 1940 vulcanite was the most widely used as denture
base material
It become unhygienic due to uptake of saliva
So acrylic resin is used almost universally for denture base
construction
HISTORY
4
Nitrocellulose
Phenol formaldehyde
Vinyl plastics
Porcelain
Metallic Non-metallic
Cobalt chromium
- Acrylic resins
Gold alloys
- Vinyl resins
Aluminium
Stainless steel
Based on Mode of Activation
Heat Activated
Chemically Activated
Light Activated
Depending on duration
Temporary
Permanent
2 .Denture Base
Materials
Temporary
Eg. Self cure Permanent
Shellac base plate
Eg. Heat cure denture resins
Base plate wax
Light cured resins
Injection molded resins
Metallic bases Pour type resins
Based on processing technique
Compression moulding
Fluid resin techique
Injection moulding
Microwave irradiation
CLASSIFICATIONS
(2) Thermosetting
Injection Autopolym
Heat cured molded
PMMA . PMMA
Conventio High
nal impact PMMA Nylon
Polycarbo
nate
Unfilled Reinforced
Carbon Polyfibre
Classification of denture base polymer according to
ISO 1567
13
polymerization(GPT 9)
CO-POLYMERS
Polymer molecules may be prepared from a mixture of
different types of monomers & they are called CO-
POLYMERS.
Degree of polymerization
It is defined as total number of mers in a polymer.
degree of polymerization.
POLYMERIZATION
The forming of a compound by joining together of
molecules of small molecular weight into a compound of
large molecular weight,reaction uses chemical,heat or
light activation.(GPT 9)
Types of polymerization.
Addition Polymerization
Condensation Polymerization
Manipulation of Denture Base Resin
Physical Stages
Sandy
Stiff Stage
Sandy Stage
Stringy Stage
Monomer attacks the surface of the Polymer beads,
penetrates into the polymer
This penetrated monomer uncoils the polymer chain
which results in increase in viscosity
Exhibits stringiness or adhesiveness.
Dough Stage
Stiff Stage
When all the free monomer get evaporated the material
becomes stiff
It becomes hard, dry and resistant to mechanical
deformation
CHEMICAL STAGES OF POLYMERIZATION
21
INDUCTION
PROPAGATION
TERMINATION
CHAIN TRANSFER
Induction – [Initiation]
• Initiator molecule (eg.benzoyl peroxide) becomes
energized & activated.
• Releases free radials which initiate polymerization.
• Initiation Energy : 16000 to 29000 cal / mol for
each monomer.
Propagation
•Theoretically reaction continues until all monomer is
converted to polymer
• Practically polymerization is never complete.
•( Residual monomer is always there).
3. Termination / chain transfer
The reaction is completed by transfer of active state
from the activated radial to an inactive molecule & thus
forming a new nucleus of growth.
Inhibitiors
1. Impurities / Retarders
eg. Hydroquinone, organic oils ( like vaseline)
- They react with activated initiator ( benzoyl peroxide)
or activated growing chain & prevent further growth.
2. Oxygen
Properties of denture base resins
Tensile and compressive strength
Both PMMA and Poly Vinylacrylic have adequate strength.
Impact strength
It is the measure of energy absorbed by the material when it
is broken
Impact strength of polyvinylacrylics is twice that of PMMA
Fatigue strength
Represents the number of cycles before failure at a certain
stress.
Fatigue strength of PMMA was higher than polyvinyl acrylic
Compressive creep
When a denture base resin are placed under load they will
deform with time
Lowest creep rates for heat-polymerised materials
Fracture toughness
Thermal conductivity
Dental resins are poor thermal conductors
Hence it serves as insulator between the oral tissues and
hot or cold food
Specific heat
It is the heat required to raise the temperature of a gram of
plastic through 1deg C
Specific heat for PMMA and polyvinyl acrylic are similar
Higher the value greater the diffusivity of heat
Crazing:
It is a small linear cracks that appear to originate at
denture surface.
It imparts hazy or foggy appearance.
Crazing is avoided by
Metal moulds
Porosity
It may be
Internal porosity
External porosity
Internal porosity
External porosity
Lack of homogeneity may lead to localized shrinkage
porosity.
Lack of adequate pressure – the voids are irregular in shape.
Denture warpage
Composition
Powder
Pre-polymerised poly methyl methacrylate
Benzoyl peroxide - initiator- 0.5%
Zinc or titanium oxide-opacifiers
Dibutyl phthlate - plasticizer- 10%
Dyed organic filler and inorganic particles like glass
fibres or beads
Compound of mercuric sulphide,cadmium
sulphide,ferric oxide- dyes
Liquid
Methyl methacrylate
Dibutyl pthlate-plasticizer - 10%
Glycol dimethacrylate -cross-linking agent
Hydroquinone –inhibitor prevents setting - 0.003%-
0.1%
Manipulation of Denture Base Resin
Compression moulding
Injection moulding
Fluid resin technique
Microwave
Visible light curing
Compression Moulding Technique
Packing
Curing
Cooling
Deflasking
Cellulose lacquers
Calcium oleate
Soft soaps
Sodium silicate
Starches.
Sodium alginate solution
Most popular
It is water soluble
Water
Glycerine
Alcohol
termed as packing.
The resin is packed using hydraulic or mechanical press.
Cooling
The flask is slowly cooled to prevent warpage.
Bench cooling for 30 minutes followed by tap water for 15
minutes.
Problems & solutions in Flasking
Self curing
Autopolymerizing resin
Composition:
LIQUID
Methyl methacrylate monomer dissolves polymer
Dimethyl ptoulidine activator
Dibutyl phthalate plasticizer
Glycol dimethacrylate cross linking agent
Hydroquinone inhibitor
Powder:
Polymethyl methacrylate dissolved by monomer to
form dough.
Benzoyl peroxide initiator
Sprinkle on technique
Adapting technique
No trial closures
Disadvantages:
Increase in cost
1.Air inclusion
2.Shifting of teeth during processing
3.Infraocclussion (closed bites)
4.Occlusal imbalance due to shifting of teeth
5.Incomplete flow of denture base material over neck of
anterior teeth.
6.Poor bonding to plastic teeth
7.Technique sensitivity.
Microwave Energy Polymerisation
Reported by Nishii
Polymerisation cycle:-
Short cycle:-500w at 3min,output energy is 90kJ
Long cycle:-90w for 13min,output 130.2kJ
Microwave energy for injection moulding technique
Curing cycle:-750W at 7min
Dimensional accuracy of denture resin cured
by microwave energy
By Phillip wallace & Gerald Graser J.P.D VOL. 66 SEP.91
Microwave processed had equal or better dimensional accuracy
than conventionally processed bases.
JPD oct.1985,vol.54,no.4;543-546
N.Yazdanie, M.Mahmood
Schrieber added carbon fiber to acrylic resin to improve
transverse strength
Carbon fiber made in 19th century by Edison obtained
from carbonizing thin bamboo shoots & cotton fibers
Bulk is made from Poly acrylonitrile heating in air at
200ºC to250ºC & then in inert atmosphere at 1200ºC
This removes H2, N2,O2. Leaving a chain of carbon
atoms / carbon fibers
NYLON or POLYAMIDES
Acrylic resins with improved thermal
conductivity
1. Repair resins
Fractures of denture may be repaired using compatible
resins.
Repair resins may be light activated, heat activated or
chemically activated.
Fractured components of prosthesis are realigned.