• Shear stress may be defined as: 𝐹 𝑉 =𝜇 𝐴 𝑌 • Thus in terms of differentials we have 𝑑𝑣𝑥 𝜏𝑦𝑥 = −𝜇 𝑑𝑦 • Fluid that follows the Newton’s Law of Viscosity is called the Newtonian fluids • Polymeric liquids, suspensions, pastes, slurries and other complex fluids are referred to as non-Newtonian fluids Non-Newtonian Fluids • Bingham Plastics –differ only from Newtonian Fluid only in that the linear relationship[ does not go thru the origin. A finite yield stress (𝜏0 ) is needed to initiate flow. – Examples are drilling muds, peat slurries, margarine, chocolate mixtures, greases, soap, grain-water suspensions, toothpaste, paper pulp and sewage sludge 𝑑𝑣𝑥 𝜏𝑦𝑥 = −𝜇 + 𝜏0 𝑑𝑦 • Pseudoplastic fluids-as shear rate increases, shear stress decreases – Examples are polymer melts, greases, starch suspension, mayonnaise, biological fluids, detergent slurries, dispersion media in certain pharmaceuticals and paints – Follows the power-law model 𝑛 𝑑𝑣𝑥 𝜏𝑦𝑥 = 𝐾 − 𝑛<1 𝑑𝑦 K- consistency index (N-sn/m2), n – flow behavior index, dimesionless 𝑑𝑣𝑥 𝑛−1 Apparent viscosity: 𝜇 𝑎 = 𝐾 − 𝑑𝑦 • Dilatant Fluids – far less common than pseudoplastics – as shear rate increases, shear stress increases exponentially – Power law model: 𝑛 𝑑𝑣𝑥 𝜏𝑦𝑥 = 𝐾 − 𝑛>1 𝑑𝑦 – Examples are flour-sugar solutions, wet beach sand, starch in water, potassium silicate in water, and some solutions containing high concentration of powder in water GENERALIZATION OF NLV • NLV we have discussed is based on unidirectional flow. • But consider the flow is multidirectional: components of velocity vector 𝐯 is 𝑣𝑥 , 𝑣𝑦 and 𝑣𝑧 • There are three forces possessed by the fluid: – Pressure forces – forces perpendicular to the exposed surface (has 3 components: 𝑝𝛿𝑥 , 𝑝𝛿𝑦 and 𝑝𝛿𝑧 ) – Gravity forces – pull of gravity on the fluid’s weight – Viscous forces – forces when there are velocity gradients within the fluid; at some angle to the surface. Has 9 components (a tensor): 𝜏𝑥 : 𝜏𝑥𝑥 , 𝜏𝑥𝑦 , 𝜏𝑥𝑧 𝜏𝑦 : 𝜏𝑦𝑥 , 𝜏𝑦𝑦 , 𝜏𝑦𝑧 𝜏𝑧 : 𝜏𝑧𝑥 , 𝜏𝑧𝑦 , 𝜏𝑧𝑧 • If we neglect gravity force, the sum of pressure and viscous forces is called molecular stress: 𝜋𝑖𝑗 = 𝑝𝛿𝑖𝑗 + 𝜏𝑖𝑗 • Restriction: – Viscous forces are linear combination of all velocity gradients (has 81 quantities of viscosity coefficients ): 𝑑𝑣𝑘 𝜏𝑖𝑗 = − σ𝑘 σ𝑙 𝜇𝑖𝑗𝑘𝑙 𝑑𝑥𝑙 – Neglect time derivatives and time integrals – If the fluid is in pure rotation, we do not expect viscous forces. Thus, the only symmetric linear combinations of velocity gradients are 𝑑𝑣𝑗 𝑑𝑣𝑖 𝑑𝑣𝑥 𝑑𝑣𝑦 𝑑𝑣𝑧 + and + + 𝛿𝑖𝑗 𝑑𝑥𝑖 𝑑𝑥𝑗 𝑑𝑥 𝑑𝑦 𝑑𝑧 • If the fluid is isotropic (no preferred direction), the expression in front of the two expression is scalar: 𝑑𝑣𝑗 𝑑𝑣𝑖 𝑑𝑣𝑥 𝑑𝑣𝑦 𝑑𝑣𝑧 𝜏𝑖𝑗 = 𝐴 + +𝐵 + + 𝛿𝑖𝑗 𝑑𝑥𝑖 𝑑𝑥𝑗 𝑑𝑥 𝑑𝑦 𝑑𝑧 2 • Dynamicists set 𝐵 = 𝜇 − 𝜅, 𝜅 is dilatational 3 viscosity and 𝐴 = 𝜇, thus 𝜏𝑖𝑗 𝑑𝑣𝑗 𝑑𝑣𝑖 =𝜇 + 𝑑𝑥𝑖 𝑑𝑥𝑗 2 𝑑𝑣𝑥 𝑑𝑣𝑦 𝑑𝑣𝑧 + 𝜇−𝜅 + + 𝛿𝑖𝑗 3 𝑑𝑥 𝑑𝑦 𝑑𝑧 • In terms of the vector tensor notation: + 2 𝛕 = −𝜇 𝛻𝐯 + 𝛻𝐯 + 𝜇−𝜅 𝛻⋅𝐯 𝛅 3 • Just read about the viscosity of liquids, gases and emulsions and their dependency on temperature, pressure and porosity Convective Momentum Transport • Momentum can be transported by the bulk flow of the fluid • Consider a volume of fluid in the figure • Thus the total flux of the x-directed flow: 𝜌𝑣𝑥 𝐯 → 𝜌𝑣𝑥 𝑣𝑥 , 𝜌𝑣𝑥 𝑣𝑦 , 𝜌𝑣𝑥 𝑣𝑧 y-directed flow: 𝜌𝑣𝑦 𝐯 → 𝜌𝑣𝑦 𝑣𝑥 , 𝜌𝑣𝑦 𝑣𝑦 , 𝜌𝑣𝑦 𝑣𝑧 z-directed flow: 𝜌𝑣𝑧 𝐯 → 𝜌𝑣𝑧 𝑣𝑥 , 𝜌𝑣𝑧 𝑣𝑦 , 𝜌𝑣𝑧 𝑣𝑧 • to generalize: 𝜌𝐯𝐯 = σ𝑖 𝛿𝑖 𝜌𝑣𝑖 𝐯 = σ𝑖 𝛿𝑖 𝜌𝑣𝑖 σ𝑗 𝛿𝑗 𝑣𝑗 𝜌𝐯𝐯 = σ𝑖 σ𝑗 𝛿𝑖 𝛿𝑗 𝜌𝑣𝑖 𝑣𝑗 Combined momentum flux • Total of molecular stresses and convective transport 𝛟 = 𝛑 + 𝜌𝐯𝐯 = 𝑝𝛅 + 𝛕 + 𝜌𝐯𝐯 • Examples: