Professional Documents
Culture Documents
Paul Gilletti
1
Instructions: This is a work along tutorial. Each time you
click the mouse or touch the space bar on your computer, one
step of the problem solving occurs. Pressing the PAGE UP key
will backup the steps.
2
(1-2-3) General Approach For Problem Solving:
1. Clearly identify the Goal or Goals and the UNITS involved. (What
are you trying to do?)
3. Use conversion factors (which are really ratios) and their UNITS to
CONVERT what is given into what is desired.
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Table of Contents: Click on each tab to view problem types.
Sample problem 1
Sample problem 2
10 miles
Given Goal
-2
45 mi 5280 ft 12 in 2.54 cm 1 x 10 k hr min
= 0.020 km
hr mi 1 ft 1 in c 1 x 10 3 60 min 60 s s
This is
c cancels c
the
m remains
same as Units Match!
putting
k over k 6
Converting grams to moles.
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Mole – Mole Conversions
When N2O5 is heated, it decomposes:
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Gram to Gram Conversions
Aluminum is an active metal that when placed in hydrochloric acid
produces hydrogen gas and aluminum chloride. How many grams of
aluminum chloride can be produced when 3.45 grams of aluminum are
reacted with an excess of hydrochloric acid?
We
Now
Now
Let’s
must
use
use
work
the
always
themolar
the
molar
problem.
convert
mass
ratio.to
convertmoles.
to grams. 13
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Molarity
moles moles
M= =
Liter 1000 mL
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Solutions
A solution is prepared by dissolving 3.73 grams of AlCl3 in
water to form 200.0 mL solution. A 10.0 mL portion of
the solution is then used to prepare 100.0 mL of solution.
Determine the molarity of the final solution.
What type of
problem(s) is
this?
Molarity
followed by
dilution.
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Solutions
A solution is prepared by dissolving 3.73 grams of AlCl3 in
water to form 200.0 mL solution. A 10.0 mL portion of
the solution is then used to prepare 100.0 mL of solution.
Determine the molarity of the final solution.
1st :
3.73 g mol
= 0.140 mol
133.4 g 200.0 x 10-3 L L
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Solution Stoichiometry
50.0 mL of 6.0 M H2SO4 (battery acid) were spilled and
solid NaHCO3 (baking soda) is to be used to neutralize the
acid. How many grams of NaHCO3 must be used?
H2SO4(aq) + 2NaHCO3 → 2H2O(l) + Na2SO4(aq) + 2CO2(g)
50.0 mL ? g Our Goal
6.0 M
Look!
=
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Solution Stoichiometry
50.0 mL of 6.0 M H2SO4 (battery acid) were spilled and
solid NaHCO3 (baking soda) is to be used to neutralize the
acid. How many grams of NaHCO3 must be used?
H2SO4(aq) + 2NaHCO3 → 2H2O(l) + Na2SO4(aq) + 2CO2(g)
50.0 mL ? g Our Goal
6.0 M
=
6.0 mol
L
H2SO4 NaHCO3 NaHCO3
50.0 mL 6.0 mol H 2SO 4 2 mol 84.0 g
= 50.4 g NaHCO3
1000mL 1 mol mol
H 2 SO 4
H2SO4 NaHCO3
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Solution Stoichiometry:
2
____NaOH 1 2SO4
+ ____H 2 2O
____H + 1 2SO4
____Na
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Solution Stoichiometry:
2
____NaOH 1 2SO4
+ ____H 2 2O
____H + 1 2SO4
____Na
0.102 M mol 35.0 mL
L 0.125 mol 0.125 mol
? mL =
L 1000 mL
Our Goal
Since 1 L = 1000 mL, we can use
this to save on the number of conversions
2
____NaOH 1 2SO4
+ ____H 2 2O
____H + 1 2SO4
____Na
0.102 M mol 35.0 mL
L 0.125 mol 0.125 mol
? mL sho =
rtcu L 1000mL
t
Units Match
H2SO4 H2SO4 NaOH
35.0 mL 0.125 mol 2 mol 1000 mL NaOH = 85.8 mL NaOH
1000 mL 1 mol 0.102 mol NaOH
H2SO4 H2SO4
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Solution Stoichiometry
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Solution Stochiometry Problem:
2
____HCl(aq) + 1
____Ba(OH) 2 1
2(aq) ____H2O(l) + ____BaCl2(aq)
23.28 mL 25.00 mL
0.135 mol ? mol
L L
2
____HCl(aq) + 1
____Ba(OH) 2 1
2(aq) ____H2O(l) + ____BaCl2(aq)
23.28 mL 25.00 mL
? mol Units match on top!
0.135 mol
L L
We must first
write a balanced
equation.
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Solution Stochiometry Problem:
units match!
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Limiting/Excess/ Reactant and Theoretical Yield Problems :
Potassium superoxide, KO2, is used in rebreathing gas masks to generate oxygen.
a. How many moles of O2 can be produced from 0.15 mol KO2 and 0.10 mol H2O?
b. Determine the limiting reactant.
4KO2(s) + 2H2O(l) → 4KOH(s) + 3O2(g)
Nowthe
First copy down place
numerical the
the BALANCED
information below
equation!
the compounds.
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Limiting/Excess/ Reactant and Theoretical Yield Problems :
Potassium superoxide, KO2, is used in rebreathing gas masks to generate oxygen.
a. How many moles of O2 can be produced from 0.15 mol KO2 and 0.10 mol H2O?
b. Determine the limiting reactant.
4KO2(s) + 2H2O(l) → 4KOH(s) + 3O2(g)
0.15 mol 0.10 mol ? moles
Hide
one
Two starting
amounts?
Where do we
start?
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Limiting/Excess/ Reactant and Theoretical Yield Problems :
Potassium superoxide, KO2, is used in rebreathing gas masks to generate oxygen.
a. How many moles of O2 can be produced from 0.15 mol KO2 and 0.10 mol H2O?
b. Determine the limiting reactant.
4KO2(s) + 2H2O(l) → 4KOH(s) + 3O2(g)
0.15 mol 0.10 mol
Hide ? moles
Based on: 3mol O 2
0.15 mol KO2
KO2 = 0.1125 mol O2
4mol KO 2
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Limiting/Excess/ Reactant and Theoretical Yield Problems :
Potassium superoxide, KO2, is used in rebreathing gas masks to generate oxygen.
a. How many moles of O2 can be produced from 0.15 mol KO2 and 0.10 mol H2O?
b. Determine the limiting reactant.
4KO2(s) + 2H2O(l) → 4KOH(s) + 3O2(g)
0.15 mol
Hide 0.10 mol ? moles
Based on: 3mol O 2
0.15 mol KO2
KO2 = 0.1125 mol O2
4mol KO 2
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Limiting/Excess/ Reactant and Theoretical Yield Problems :
Potassium superoxide, KO2, is used in rebreathing gas masks to generate oxygen.
4KO2(s) + 2H2O(l) → 4KOH(s) + 3O2(g)
a. How many moles of O2 can be produced from 0.15 mol KO2 and 0.10 mol H2O?
Determine the limiting reactant.
4KO2(s) + 2H2O(l) → 4KOH(s) + 3O2(g)
0.15 mol 0.10 mol ? moles
Based on: 3mol O 2
0.15 mol KO2
KO2 = 0.1125 mol O2
4mol KO 2 It was limited by the
amount of KO2.
Based on: 0.10 mol H2O 3mol O 2
= 0.150 mol O2
H2 O 2mol H 2O
H2O = excess (XS) reactant!
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Limiting/Excess Reactant Problem with % Yield
Question if only 35.2 g of O2 were recovered, what was the percent yield?
actual 35.2
x 100 = x 100 = 86.9% yield
theoretical 40.51
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If a reaction vessel contains 120.0 g of KO2 and 47.0 g of H2O,
how many grams of O2 can be produced?
4KO2(s) + 2H2O(l) → 4KOH(s) + 3O2(g)
120.0 g 47.0 g ?g
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