Professional Documents
Culture Documents
Introduction
• What ?
• Why?
• Feed Stock?
• Production?
• Biodiesel blends
• Key Issues?
• commercialization
Bio Fuels for Automotive Use SIAM
AUTO F U E L
MATERIALS
BIO RAW
Trans-
Vegetable Oil Bio-Diesel
Esterification
3
What is Biodiesel ? SIAM
4
What is Biodiesel ? Contd…..SIAM
Bio-Diesel may be in the form of :
Fatty Acid Methyl Ester or Fatty Acid Ethyl Ester
Main Characteristics:
• Better lubricity
• High Flash Point
• Comparable Heating Value content
• Readily mixes with diesel
• Ready to use in diesel run engines
5
BIODIESEL
CONCEPT
Diesel (Petroleum derived) Oil When
Substituted Partly or Wholly by a Liquid
Fuel Derived from Renewable Resource
Materials is Coined as ‘Biodiesel’.
PRODUCT DEFINITIONS
BIODIESELS- Mono-alkyl esters of long chain
fatty acids derived from
vegetable oils or animal fats
BIODIESEL BLENDS (Bxx)- Blends of biodiesel
fuel with petroleum based diesel
fuel.
Reminder: Diesel Fuel is a middle distillate fuel designed (per ASTM D 975)
for diesel engines
BIODIESEL AND BIODIESEL BLENDS
Biodiesel Blends
100
Blend Percentage (%)
90
80
70
60
50 Biodiesel
Diesel
40
30
20
10
0
B2 B5 B20 B100
Source: www.afdc.doe.gov
Trans-esterification Process SIAM
15
Production Of Biodiesel
BIODIESEL AND BIODIESEL BLENDS
Biodiesel Raw Materials
Source: www.afdc.doe.gov
Biodiesel can be used
in existing Diesel
Engines
• Pure Biodiesel (B100) or blended with petroleum
diesel (B20, BXX).
• Rudolf Diesel: peanut oil.
• Little or no engine modifications
• Use existing fuel distribution network.
• Available now
Relative Greenhouse Gas
Emissions
B100 B100 = 100% Biodiesel
B20 = 20% BD + 80% PD
Electric
Diesel Hybrid
B20
Ethanol 85%
Diesel
LPG
CNG
Gasoline
R1, R2, and R3 are fatty acid alkyl groups (could be different, or the
same), and depend on the type of oil. The fatty acids involved determine
the final properties of the biodiesel (cetane number, cold flow properties,
etc.)
Individual step of Transesterification
First step, triglyceride turned into diglyceride, methoxide
(minus Na) joins freed FA to make biodiesel, Na joins
OH from water (from methoxide formation) to make
NaOH. Other H joins the diglyceride.
H O H
| | |
HCOR1 H HCO H O
| | | | |
HCOOR2 + HCONa +H2O CHOOR2 + HCOR1 + NaOH
| | | |
HCOR3 H HCOR3 H
| | | |
H O H O
Oilseed
Meal
Farming
Energy Crop
R&D Crushing
Crop Oil
Biodiesel