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Removal of pollutants from exhaust gas after they leave the engine cylinder can be done either by using a thermal reactor or by using a catalytic converter In order to oxidize HC in the gas phase without catalyst a residence time of the order of 50ms and temp of about 6000 C is required. Whereas to oxidize CO temp in excess of 7000C is required.
Thermal Reactors
HC and CO can be reduced by using thermal reactors. Reactors are designed to reduce heat loss of the gas in the exhaust manifold and increase residence time of the gas in the exhaust manifold. Typically a thin steel liner acts as reactor core. Heat losses are minimized by insolating the reactor core. The reactor core is kept in a CI casing.
Denox Catalytic Converters Denox catalytic converters allow not only CO and HC reduction but also NOx reduction at lean mixture. They are currently at development stage.
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Metal Substrate
Now a days metallic substrates are also available. Their advantages are: Increased conversion efficiency Longer life Lower wall thickness (0.04 to 0.06 mm) More No. of cells can be use per unit area. WASHCOAT Washcoat is applied to substrate material. It has a surface area of 100-200 m2/g. 100-
Catalysts
Catalysts used in a 3 way CC are Pt, Pd & Rh. A very small amount of Pt, Pd & Rh is impregnated into highly porous alumina washcoat. For oxidation of CO and HC a mixture of Pt and Pd is most commonly used. For oxidation of CO, olefins and CH4 specific activity of Pd is higher than that of Pt. For oxidation of aromatic compounds Pt and Pd have similar activity. For oxidation of paraffinic HCs (<C3) Pt is more active than Pd.
Catalysts Contd.
Noble metals sinter rapidly at 5000 C to 9000 C. Noble metals are dispersed as finely as possible in alumina which prevents particle to particle metal contact and supress sintering. Particle size of noble metal is 50 nm. This can increased to about 100 nm when exposed to high temperature.
Catalysts--contd. Catalysts--contd. Pt/Pd = 2 is typical in a three way catalytic converter. Concentration of noble metal is about 1-2 g/dm3 1-
Conversion efficiency of a CC
Conversion efficiency = (min mout)/min = 1 mout/min
Effect of A/F on
conv
of CC