Results Average emf of the different electrodes Electrodes Anode (-) Cathode (+) Average emf (v) Zn/Zn2+ & Zn/Zn2+ Pb/Pb2+ 0.565 Pb/Pb2+ Zn/Zn2+ & Zn/Zn2+ Fe/Fe3+ 0.456 Fe2+,Fe3+ Pb/Pb2+ & Pb/Pb2+ Fe/Fe3+ 0.064 Fe2+,Fe3+ Cu/Cu2+ & Pb/Pb2+ Cu/Cu2+ 0.0585 Pb/Pb2+ Al/Al3+ & Al/Al3+ Pb/Pb2+ 0.1225 Pb/Pb2+ Results Cell Diagrams Electrodes Cell Diagram Zn/Zn2+ & Pb/Pb2+ Zn| ZnSO4(aq)||Pb(NO3) 2(aq) |Pb Zn/Zn2+&Fe2+,Fe3+ Zn| ZnSO4(aq)||Fe3+ (aq)|Fe Pb/ Pb2+&Fe2+,Fe3+ Pb|Pb(NO3) 2(aq)|| Fe3+ (aq)|Fe Cu/Cu2+ & Pb/Pb2+ Pb|Pb(NO3) 2(aq)||CuSO4(aq)|Cu Al/Al3+ & Pb/Pb2+ Al|Al(NO3) 2(aq))||Pb(NO3) 2(aq)|Pb Results Overall reaction and Theoretical emf Electrodes Overall Reaction emf (theo) (V) Zn/Zn2+ & Zn+Pb2+ → Zn2+ +Pb 0.636 Pb/Pb2+ Zn/Zn2+&Fe2+, Zn+Fe3+ → Zn2++Fe 0.721 Fe3+ Pb/ Pb+Fe3+ → Pb2+ +Fe 0.079 Pb2+&Fe2+,Fe3+ Cu/Cu2+ & Pb+Cu2+ → Cu+Pb2+ 0.465 Pb/Pb2+ Al/Al3+ & Al+Pb2+ → Pb+ Al3+ 1.551 Pb/Pb2+ Results Comparison of Experimental Data with Theoretical Data Electrodes emf emf % error (theoretical) (experimental) Zn/Zn2+ & 0.636 0.565 11.16% Pb/Pb2+ Zn/Zn2+&Fe2+, 0.721 0.456 35.75% Fe3+ Pb/ 0.079 0.064 18.99% Pb2+&Fe2+,Fe3+ Cu/Cu2+ & 0.465 0.0585 87.42% Pb/Pb2+ Al/Al3+ & 1.551 0.1225 92.10% Pb/Pb2+ Conclusion The experiment was able to meet its objective having come up with the values of the electromotive force of each galvanic cell. Although the experimental data had resulted to a significant deviation from the computed values due to process errors, the positive values of the experimental data implies that all the reaction are spontaneous. Recommendations the materials involved should be cleaned properly best to use a digital multimeter highest emf reading that should be recorded salt bridge should be maintained wet with KCl solution in weighing the solutes, getting the exact weight is not a necessity Questions 1. How 1. Whatiscould the significance have happened of electron if the alligator affinity and clipselectron were also negativity submergedof the into electrodes the solution on the whenmefthe ofhalf-cells the galvanic werecell? being Explain prepared? briefly How would this affect the result of the experiment and why? 2. What does a negative readfing in the multimeter indicate? 3. How would the result of the experiment be affected if the electrodes of the half-cells were interchanged instead of the multimeter terminal?