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Atoms and subatomic particles Elements (Periodic Table) Isotopes (Chart of Nuclides) Nuclear forces, stability, and binding energy Radioactive decay
Atoms are the smallest unit of a chemical element that has all the chemical properties of that element. Made up of:
Protons positive charge Neutronsno charge Electronsnegative charge
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VIIIA
8A 2 IIA 2A
4
H
1.008 3
He
4.003 10
Li
6.941 11
Be
9.012 12 24.31
B
8 9 10 11 12 3 4 5 6 7 IIIB IVB VB VIB VIIB ------- VIII --- IB IIB ---3B 4B 5B 6B 7B 1B 2B ------- 8 ------21 22 23 24 25 26 27 28 29 30 13
C
14
N O
15 16
F
17
Ne
20.18 18
Na Mg
22.99 19 20
Al Si
31 32
P
33
S
34
Cl
35
Ar
39.95 36
K
39.10 37
Ca
40.08 38
Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br
44.96 47.88 50.94 52.00 54.94 55.85 58.47 58.69 63.55 65.39 69.72 72.59 74.92 78.96 79.90 39 40 41 42 43 (98) 75 44 45 46 47 48 49 50 51 52 53
Kr
83.80 54
Rb
85.47 55
Sr
87.62 56 137.3 88 (226)
Y
57
Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te
72 73 74 76 77 78 79 80 81 82 83 84
I
85
Xe
131.3 86 (222) 118
101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9
Cs
132.9 87
Ba La* Hf Ta W Re Os
89 104 105 106 107 108
Ir
109
Pt Au Hg Tl Pb Bi Po At Rn
110 () 111 () 112 () 114 116
138.9 178.5 180.9 183.9 186.2 190.2 190.2 195.1 197.0 200.5 204.4 207.2 209.0 (210) (210)
Fr
(223)
Ra Ac~ Rf Db Sg Bh Hs Mt --- --- --(227) (257) (260) (263) (262) (265) (266)
--()
--()
--()
Lanthanide Series*
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59
60
61
62
63
64
65
66
67
68
69
70
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Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.1 140.9 144.2 (147) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0 90 91 92 93 94 95 96 97 98 99 100 101 102 103
Actinide Series~ Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.0 (231) (238) (237) (242) (243) (247) (247) (249) (254) (253) (256) (254) (257)
A Z
XN
Z is the atomic (proton) number N is the neutron number A is the mass number (N+Z) X is the chemical element symbol
Atoms and Isotopes 6
Isotopes
Atoms of one element may have different number of neutrons: the different possible versions of each element are called isotopes. Isotopes of one element all have the same number of protons (atomic number, Z) but different numbers of neutrons (thus different atomic weights, A).
Isotopes of the element sodium 11 protons Isotopes of the element oxygen 8 protons
Nuclear Forces
Particles with like charges repel. This causes electrons to orbit around the nucleus.
Nuclear Forces
Particles in the nucleus actually are held together by an even stronger attractive force. Acts only at very short distances (about 10-15m)beyond this distance, the strong nuclear force is negligible.
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Nuclear Forces
Two protons more than 10-15m will repel each other by their like charges. Inside a nucleus, the distances are small enough that the strong nuclear force overcomes the weak repulsive force, holding the protons and neutrons together.
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Nuclear Forces
Big Idea of Science:
There are only four known forces in nature:
1. 2.
3.
4.
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Think about it
How might a higher number of neutrons change the balance between the repulsive and attractive forces in a nucleus? How might a lower number of neutrons affect this same balance?
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Nuclear Stability
The stability of an atom is the balance of the repulsive and attractive forces within the nucleus (strong and weak force in equilibrium).
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Nuclear Stability
If
If
the repulsive weak forces outweigh the attraction of the strong forces, the nucleus is unstable.
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Nuclear Stability
For elements with low atomic numbers, atoms are stable when their neutron to proton ratio is close to one (1:1).
As atomic number increases, stable atoms have ratios greater than one (1:1.5).
This is because at higher atomic numbers, more neutrons are needed to counteract the repulsive forces between the protons.
Atoms and Isotopes 16
Nuclear Stability
The shaded cluster is the band of stability. The solid line represents a neutronto-proton ratio of 1:1. Nuclei to the right of the band of stability dont have enough neutrons to remain stable. Nuclei to the left of the band have too many neutrons to remain stable.
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The energy stored in the bonds within an atom Released when an atom breaks apart Represented by the equation:
Eb (MeV) = (Zmp + Nmn MA) x 931.494 MeV/amu Where:
1 amu = 1.66 x 10-24 grams [amu = atomic mass unit] Eb= binding energy Zm= mass of the protons in amu Nm= mass of neutrons MA= mass of the atom MeV= millions of electron volts, a unit of measure used to represent the energy in nuclear equations
Atoms and Isotopes 18
Radioactive Decay
Unstable atoms will spontaneously transform until they reach a stable configuration. These transformations are accompanied by releases of energy.
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Radioactive Decay
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Radioactive Decay
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Radioactive Decay
Alpha emission () Nucleus emits an alpha particletwo protons and two neutrons Equivalent to a helium nucleus (He).
238 92
U Th + He
Atoms and Isotopes 22
234 90
4 2
Radioactive Decay
Beta Emission () Nucleus emits an electron, and a neutron is converted to a proton.
131 53
I Xe + e
Atoms and Isotopes 23
131 54
0 -1
Radioactive Decay
Positron Emission Nucleus emits a positron (identical to an electron in mass, but has a positive charge)
11 6
C B+ e
11 5
0 1
Radioactive Decay
Gamma emission ()
Nuclei seeking lower energy states emit electromagnetic radiation, which is in the gamma ray region of the electromagnetic spectrum. Rays are emitted in conjunction with another type of decay (alpha or beta).
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Half Life
The amount of time it takes for half of the atoms of a given isotope to decay to another form is known as its half-life. The value can be from fractions of a second to billions of years.
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Half Life
Half-life values are constant. There is no way to speed up or slow down this natural process. Cannot predict when a specific atom will decay. Can predict the number of atoms that will decay in a certain time period.
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Words to Know
Alpha decay Atom Beta decay Chart of Nuclides Coulombs force Electron Electron capture Element Gamma decay Half-Life Isotope
Neutron Nuclear force Nucleus Nuclide Periodic Table Positron Proton Radiation Radioactive Decay Stability
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