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DR.DEEKSHA SHETTY
INTRODUCTION
Adhesion of restorative material to mineralized tooth structure has been a goal of dental researchers for many years. Accomplishing such a bond has many principle advantages like: 1. Retention of restoration, 2. Conservation of tooth structure, 3. Elimination of marginal microleakage, 4. Reinforcement of remaining tooth structure 5. Increasing the clinical life time of restorations.
Due to lack of adhesion between dental restorative resins and tooth structure, microleakage of salivary components and bacteria occur, which may lead to: i. Marginal staining. ii. Breakdown at the margins of the restoration interface.
iii.Secondary caries.
iv.Post operative sensitivity. v. Pulp pathology.
TERMINOLOGIES
Acid-Etching- Process of roughening a solid surface by exposing it to an acid and thoroughly rinsing the residue to promote micromechanical bonding of an adhesive to the surface. Adhesion- A molecular or atomic attraction between two contacting surfaces promoted by the interfacial force of attraction between the molecules or atoms of two different species; adhesion may occur as physical adhesion, chemical adhesion, mechanical adhesion (structural interlocking) or a combination of all types. Adhesive- Substance that promotes adhesion of one substance or material to another. Adherend- A material substrate that is bonded to another material by means of an adhesive.
Adhesive Bonding- Process of joining two materials by means of an adhesive agent that solidifies during the bonding process. Dentin Bonding- The process of bonding a resin to conditioned dentin. Dentin Bonding Agent- A thin layer of resin between conditioned dentin and the resin matrix of a composite. Dentin Conditioner- An acidic agent that dissolves the inorganic structure in dentin, resulting in a collagen mesh that allows infiltration of an adhesive resin. Hybrid Layer- An intermediate layer of resin, collagen, and dentin produced by acid etching of dentin and resin infiltration into the conditioned dentin.
Microleakage- Flow of oral fluid and bacteria into the microscopic gap between a prepared tooth surface and a restorative material. Primer- A hydrophilic, low viscosity resin that promotes bonding to a substrate, such as dentin. Resin Tag- Extension of resin that has penetrated into etched enamel or dentin. Smear Layer- Poorly adherent layer of ground dentin produced by cutting a dentin surface. Wettability-Relative affinity of a liquid for the surface of a solid. Wetting- Relative interfacial tension between a liquid & the solid substrate that results in a contact angle less than 900.
An adhesive joint is the result of interactions of a layer of intermediate material (adhesive) with two surfaces (adherends) producing two adhesive interfaces. . CLASSIFICATION The interactions which occur at the interface are classified generally in terms of types of atomic interactions which may be involved. Adhesion is classified as: 1. Physical. 2. Chemical. 3. Mechanical. Micro Macro
Physical bonding involves Vander waals or other electrostatic interactions that are relatively weak. It may be the only type of bonding if surfaces are smooth and chemically dissimilar.
MECHANISMS OF ADHESION
The oral hard tissues and their environment are complex. In general, the following factors can play major or minor roles in achieving adhesive bonds: 1. Wetting 2. Interpenetration (formation of a hybrid zone) 3. Micromechanical interlocking
4. Chemical bonding
example, one can readily form strong, durable bonds between sheets of
plate glass by using an epoxy resin. This combination involves no primary chemical bonding between adhesive and adherend, no micro
Wetting of tooth structure alone does not achieve lasting intraoral bonds because the principal substrates (adherends), enamel and dentin, are hydrated, hydrophilic, and permeable to water. Such adherends require a hydrophilic, hydrolytically stable adhesive for wetting to occur. However, even if the surface is initially dried before adhesive application, diffusion results in one or more monolayers of water that strongly bond to both the tissue and the adhesive. Unfortunately, water has a very low shear strength, so the net shear bond strength between two perfectly flat surfaces is insignificant.
ACID ETCHING
Perhaps the most significant discovery in dentistry during the last three decades is that of Dr. Michael Buonocore in 1955. Working in New York, he discovered that the bonding strength between human enamel and acrylic resin could be tremendously enhanced by exposing the tooth to a mild acidic solution before applying resin to the enamel surface.
.
He etched the enamel surface with acids and then placed an acrylic
In his first experiments Dr. Buonocore was actually following the lead of industry. By the mid-1950s it was already commonplace to pre-treat surfaces, such as metals, with
Almost every case of dental adhesion is based primarily on mechanical bonding. Chemical bonding may occur as well, but generally makes only a small contribution to the overall bond strength. Common method for producing surface roughness for better mechanical bonding is to grind or etch the surface. Grinding produces gross mechanical roughness but leaves a smear layer of hydroxyapatite crystals and denatured collagen that is approximately 1 to 3 microns thick.
layer
and
produces
microscopic
relief
with
undercuts on the surface to create an opportunity for mechanical bonding. If the interlocked adhesive and adherend with dimensions less than about 10 microns, then the situation is described as micro-
mechanical bonding.
It is fortunate that there is a difference between the resistance of the enamel prisms and the inter-prismatic enamel to acidic attack. Thus, as Dr. Buonocore discovered, placing a weak acidic solution on the enamel surface causes a differential etch rate between these two areas; this results in
Type II
Acid etching of enamel is one of the most effective ways to improve mechanical bonding and to ensure sealed interfacial gaps. This procedure
interfacial leakage
Although
aqueous
fluids
available
as an aqueous gel to allow precise placement over a specific area. These gels are often made by adding colloidal silica (the same fine particles
When properly etched, the tooth should exhibit a dull, frosted, matte finish. Under-etching results in a tooth that retains its gloss. Over-etching
This surface must be kept clean and dry until the resin is placed to form a sound mechanical bond. Although enamel etching raises the surface energy of the enamel, contamination can readily reduce the energy level of the etched surface. Reducing the surface energy, in turn, makes it more difficult to wet the surface with a bonding resin that may have a higher surface energy than that of the contaminated surface. Thus even momentary contact with saliva or blood can prevent effective resin tag formation and severely reduce the bond strength. Another potential contaminant is oil that is released from the air compressor and transported along the airlines to the air-water syringe. If contamination occurs, the contaminant should be removed, and the enamel should be etched again for 10 see.
Etching of dentin leaves a sponge-like structure with little compression, tensile or shear strength (Standford 1985 ) .
Dentinal canals at the external surface of roots or near dentinoenamel junction have small diameters. Dentinal canals closer to the dental pulp become larger, older dentin has small dentinal canals. Dentinal bonding agents use some form of mechanical attachment into dentinal canals. In small canals attachment is less and in larger canals attachment is enhanced.
Materials: A surface active comonomers, Nphenylglycine glycidyl methacrylate (Bowen, 1965) was developed that acted as a primer or adhesion promoter between enamel / dentin and resin materials by chelating with surface calcium. E.g. Cervident. Disadvantages 1. Poor bond to dentin familiar amalgam type retentive cavities. 2. Used only for small class III and class V restorations where there was adequate enamel in which to bond. 3. Post operative sensitivity in attempted posterior occlusal restorations.
Materials a) Clearfil b) Scotch Bond c) Prisma Universal Bond d) Dentin Adhesit Disadvantages 1. Weak bond to dentin 2. Mechanical retention form was still necessary since bond strength alone was inadequate. 3. Margins on dentin were problematic since the low dentinal bond strengths permitted extensive marginal microleakage. 4. Restoration failure occurred most commonly due to hydrolytic decomposition.
Dentin Conditioners
:-
remove the smear layer and subsequently interact with superficial dentin and rinsed off after application.
A primer is an agent which enhances the wettability of a bonding agent onto the dentinal surface. The primer usually contains an adhesion promoter in a solvent such as water, ethanol or acetone
Materials
1) Prime & Bond 2) One Step Bond
3) Tenure Quick
4) Syntac single
5) Opti Bond
Advantages
1) Dentin bond strength are well above 15mpa.