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Outline
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Introduction/Background Features of CdTe Solar Cells Research Issues in CdTe Solar Cells Summary of Literature Review Problem Statement Research Philosophy Challenges of Flexible substrates Significance of Study Research Objectives Research Methodology Expected Outcomes Gantt Chart Selected References Some Recorded progresses
Background
World Population increases Economic growth Global energy demand rises steadily Spiraling energy cost Environmental hazards
Background contd.
There is needs for clean, cheap and environ-friendly energy
PV suffers from low efficiency and high cost Thin film PV cells are attractive, due to ease of mass production, low material usage, thus cheaper units CdTe is considered one of the most favored thin film solar cells for the future CdTe PV cells suffer from poor back contact structure, due to high potential barrier height
Shortcomings:
Lower efficiency Shorter lifetime stability
To compete with conventional sources: thin film solar cells should be 25%
Introduction
CdTe has been identified as a potential semiconductor material for thin film solar cells of the future due to its attractive features: y Its band gap of 1.5eV is ideal for optimal solar radiation absorption y Direct bandgap which makes it an excellent optical absorber y Its chemical stability, low thermal coefficient of parameters, simplicity and variety of deposition methodologies all combine to make CdTe an ideal material for thin film solar cells y There are multiple and cheap deposition processes y Also, some of these processes are adaptable to mass industrial production y High stability against particle radiation y High specific power y Lower temp coeff. efficiency at increased temperature y Better efficiency even under poor weather conditions (cloudy, dawn, dusk, dusty, snowy
substrates, using the superstrate structure y But glass-based solar cells are associated with several setbacks which include -heavy weight (where glass forms 98% of cell weight) - easy breakage, - non flexible, -difficult and expensive production process, - poor thermal conductivity and expansitivity, - poor mechanical flexibility and - low specific power
absorber, 0.10-1.00m CdS window layer y However, it has been established that a CdTe layer thickness of 1-2m is enough to absorb 90% of incident light, while a CdS layer 0.050-0.100m thick is adequate to produce an acceptable efficiency y A champion cell of 16.5% efficiency
low cost, efficient CdTe cells using ultra-thin layers y CdTe absober thickness of 0.5-1.5m have been developed on glass with reasonable performances y CSS and magnetron sputtering have been reported for these ultra thin layers y Efficiencies of 11.5% was reported at CdTe thickness of 1m and less using CSS y While 9.6% efficiency has been obtained using sputtering y Thus, ultra-thin CdTe photovoltaic solar cells are viable
ultra-thin CdTe solar cells on flexible substrates will lead to a more efficient, cheaper and simpler processes solar cells y Such cells would have important and useful applications in space applications, mobile power supply systems and Building Integrated Photovoltaic (BIPV). y It will also ease deployment, reduce the risk of breakage, requires simpler support system.
Performance Tree
Performance
Efficiency Voc
Reduce pin holes
Stability FF Materials
Reduce resistivity New materials
Jsc
optical transmission Optical absorption
Reduce resistivity
Stoichiometry
Optimize treatment
Dopants
Processes
Processes
Materials
Materials
Type of substrate
Buffer, Bilayer
dopants Polymer
Problem statement
Conventional CdTe/CdS thin film solar cells deposited on glass substrates suffer from: y Excessive weight, thus overall higher costs y Fragility, rigidity, thus difficulty and high cost of deployment y Poor thermal conductivity of glass thus problems during annealing of large area panel y Thermal stress which causes breakage during fabrication y Higher material input due to thicker layers CdTe(5-10m) y Higher optical absorption in the CdS window layer y Reduced Jsc,Voc and high Rs y Poor ohmic back contact y Higher production cost.
Research Philosophy
An Ultra-Thin CdTe Solar Cell on Flexible Substrates will Reduce Material input, weight, cost, processing complexities and ease deployment, giving a versatile, efficient, portable and cheap source of energy
it is difficult to insert a buffer interlayer onto metallic substrates y The requirements for matching the work functions and thermal coefficients of the contacting materials allow selection of only a few substrate materials. y Molybdenum is favored as substrate material due to its matching thermal expansion coefficient, but its low work function necessitates the use of an interlayer y CdCl2 annealing treatment at high temperature changes the ohmic contact properties
around 400-450oC for some commercial polymers. This limits the processes carried on the structure y Polymers have limited optical transmission, reducing the Jsc of the cell
Research Objectives
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Design and Development of ultra thin CdTe solar cell structures Simulations of the designed cells and optimization Development of a suitable Ohmic back contact structure Fabrication and optimization of complete CdTe solar cells on both polyimide and Molybdenum substrates by RF Sputtering, CSS methods Characterization of the fabricated cells and various layers using AFM, XRD, SEM, I-V, Hall effect and Electrical parameters of cells (I-V, Jsc, Voc, FF, ) Evaluation of the complete solar cells under extreme conditions of temperature and light intensity
Methodology
y Design and simulation utilizing AMPS-1D software for costeffective, high efficiency, ultra-thin CdTe solar cell. y Investigation of a low cost and highly effective fabrication process for CdTe absorber layer on metallic using Close-SpacedSublimation method. y Investigation of low temperature and low cost sputtering growth for CdTe/CdS layers on polyimide substrate y Test and measurements of the growth process of CdTe absorber layer and other layers y Optimization of fabrication process steps specially CdCl2 treatment. y In house complete fabrication of CdTe solar cells. y Evaluation of the fabricated cells in standard condition and characterization. y Measurement of the effect of operating temperature and reliability of the cell on efficiency
xpected Outcomes
y A new back contact for a more efficient, stable cell y A thinner CdTe/CdS cell structure for better material use y A flexible solar cell on metallic substrate y A flexible solar cell on polymer substrate y A complete CdTe solar cell with stable, enhanced performance and lower cost y Publications in Revered Journals and Conferences y PhD Thesis
contact material, (SnO2), (ZnO) and zinc stannate (Zn2SnO4) as buffer layer, y Silver (Ag) or antimony telluride (Sb2Te3) with (Mo) or (ZnTe) with (Al) as back contact material. y The cell structureITO/i-ZnO/CdS/CdSxTe1-x/CdTe/Ag has shown the best conversion efficiency of 16.9% (Voc: 0.9V, Jsc:26.35mA/cm2 ,FF: 0.783).
An Ultra Thin Absorber Layer with Novel Back Contact for High Efficiency CdS/CdTe Solar Cells
y The possibility of ultra thin absorber layer of CdS/CdTe cells was y y y y
investigated The CdTe absorber layer was found that 1 m is just enough for acceptable range of cell efficiencies. This ultra thin CdTe absorber layer was examined, together with As2Te3 back surface field (BSF) layer to reduce the barrier height and recombination losses Conversion efficiency of 16.65% without BSF and 18.6% (Voc = 0.92 V, Jsc = 24.97 mA/cm2 and FF = 0.81) 18.6% with As2Te3 BSF. The cells normalized efficiency linearly decreased with the increasing operating temperature at the gradient of -0.4%/C, which indicated better stability of the cells.
Conclusion
y The CdTe is a viable and strong candidate for the source of y y y y
cheap, clean energy for the future Its current efficiency, cost and performance need to be improved By using flexible substrates, numerous advantages may accrue Thinner CdTe/CdS layers with reasonable performance possible A stable back contact is necessary for better performance
Selected References
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Tiwari, A.N., Khrypunov, G., Kurdzesau, F., Batzner, D.L., Romeo, A. And Zogg, H.(2004) CdTe Solar Cell in a Novel Con guration PROGRESS IN PHOTOVOLTAICS: RESEARCH AND APPLICATIONS, 2004; 12:33 38. Mathew, X. Enriquez, J.P., Segura, G. Sanchez-Juarez' (2005) DEVELOPMENT OF A SUBSTRATE CONFIGURATION CdTe/lCdS SOLAR CELL ON FLEXIBLE MOLYBDENUM SUBSTRATE, IEEE Conference. Romeo, A. et al. (2006) High-Efficiency Flexible CdTe solar cells on Polymer Substrates Solar Energy Materials & Solar Cells 90, 3407 3415 Khrypunova et al (2006)Recent developments in Evaporated CdTe Solar Cells. Solar Energy Materials & Solar Cells 90, 664 677 Pantoja, et al (2004) CdTe/CdS Solar Cells on Flexible Molybdenum Substrates Solar Energy Materials & Solar Cells. 82, 307 314 Vijay, et al (2004) Design Issues in the Fabrication of Cds CdTe Solar Cells on Molybdenum Foil Substrates SolarEnergyMaterials&SolarCells76(2003)369 385 Tiwari, et al, (2001) Flexible CdTe Solar Cells on Polymer Films. PROGRESS IN PHOTOVOLTAICS: RESEARCH AND APPLICATIONS, 9:211-215 German, et al In uence of the Au Interlayer on the Contact Resistance and Morphology of CdTe Films Deposited on Molybdenum Substrate. Solar Energy Materials & Solar Cells 90:2289 2296 Hern, G. et al (2004) Structural Characterization of CdTe Thin Films Developed on Metallic Substrates by Close Spaced Sublimation JOURNAL OF MATERIALS SCIENCE 39, 1515 1518 Wu, X. (2004) High Efficiency Polycrystalline CdTe thin film Solar Cells, Solar Energy 77 803-814.
References contd.
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Xavier, et al (2003) Development of CdTe thin films on Flexible Substrates- A Review, Solar Energy materials & Solar Cells 76 293-303. Mathew, et al, (2004) CdTe/CdS Solar Cells on Flexible Substrates, Solar Energy 77 831-838 Singh, et al (2003)Design Issues in the Fabrication of CdS- CdTe Solar Cells on Molybdenum Foil Substrates, Solar Energy Materials and Solar Cells 76 369385 Chandramoham, et al (2006) Structural Properties of CdTe thin Films on Different Substrates, solar Energy Materials and Solar Cells 90 686-693. Dharmadasa, I.M. (2009) Latest Developments in CdTe, CuInGaSe2 an GaAs/AlGaAs Thin film PV Solar Cells. Current Applied Physics, 9 e2-e6. Gosh, B. (2009) electrical Contacts for II-VI Semiconductor Devices, Microelectronic Engineering, XXX Hadrich, et al (2009) Pathways to Thin Absorbers in CdTe Solar Cells, Thin Solid Films 517 2282-2285. Ghos, B. (2008) Work Function Engineering and its Applications in Ohmic Contact Fabrication to II-VI Semiconductors, Applied Surface Science 254 4908-4911. Romeo, et al, (2007) bifacial Configurations for CdTe Solar Cells, Solar Energy Materials & Solar Cells 91 1388-1391. Perez, et al, (2009) CdTe Solar Cell Degradation Studies with the use of CdS as the Window Material, Solar Energy Materials and Solar Cells 93 79-84.
Publications
y N. Amin, M. M. Aliyu, M. A. Matin1,, A. Islam, M. R. Karim, M. Y. Sulaiman and K.
Sopian, Prospects of Ternary CdZnTe in a Graded Bandgap Thin film Solar Cells. World Renewable Energy Congress XI, 25-30 September 2010, Abu Dhabi, UAE y M.A. Matin, M.M. Aliyu, A. Quadery, N. Amin, Prospects of novel front and back contacts for high ef ciency cadmium telluride thin film solar cells from numerical analysis, Solar Cells and Solar Materials 94 (2010) 1496-1500
y Ultra Thin Absorber Layer with Novel Back Contact for High Efficiency
CdS/CdTe Solar Cells, N. Amin , M. A. Matin, M. M. Aliyu, A.S.M. M. Zaman, K. Sopian and M. Y. Sulaiman, World Renewable Energy Congress XI,
25-30 September 2010, Abu Dhabi, UAE
Nowshad Amin, A Numerical Analysis on CdS:O Window Layer for Higher Efficiency CdTe Solar Cells, 1st International Conference on the Developments in Renewable Energy Technology (ICDRET 09), December 17-20, 2009, Dhaka Bangladesh
Publications
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M.M. Aliyu, M. A. Matin , N. Amin and K. Sopian, CdTe-Based Flexible Solar Cells on Metallic Substrates: Issues and Prospects, Proceedings of International Conference on Advances in Renewable Energy Technologies, 6-7 July 2010, Putrajaya, Malaysia M.A.Matin, M.M.Aliyu, M.R.Karim, N.Amin, M. Y. Sulaiman, K. Sopian Towards Ultra Thin and High Efficiency CdTe Solar Cell, Proceedings of International Conference on Advances in Renewable Energy Technologies, 6-7 July 2010, Putrajaya, Malaysia. Aminul Islam, M.M. Aliyu, M. A. Matin, Yusuf Sulaiman and Nowshad Amin, Investigation of the affect of window layer thickness, Temperature and Sun Intensity on four different CdTe solar cell structure by Numerical Analysis. Proceedings of International Conference on Advances in Renewable Energy Technologies, 6-7 July 2010, Putrajaya, Malaysia. M. M. Aliyu, M. A. Martin, N. Amin and M. Y. Sulaiman, Prospects of Ternary CdZnTe in a Graded Bandgap Thin film Solar Cells, World Renewable Energy Congress XI 25-30 September 2010, Abu Dhabi, UAE N. Amin, M. A. Matin, M. M. Aliyu, A.S.M M. Zaman, K. Sopian and M. Y. Sulaiman Ultra Thin Absorber Layer with Novel Back Contact for High Efficiency CdS/CdTe Solar Cells World Renewable Energy Congress XI 25-30 September 2010, Abu Dhabi, UAE