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Qatar Steel Company ( QASCO ) is the first integrated steel plant in the middle east. It was incorporated in the year 1978,in collaboration with KOBE STEEL of Japan. Qascos main products are billets and Steel bars. The main plants in QASCO are; 1- Direct Reduction Plant ( D.R ) 2- Electric Arc Furnaces ( E.F ) 3- Continuous Casting Mills ( C.C ) 4- Rolling Mills ( R.M ) QASCO receives iron ore in the form of pellet or lump ore from countries like Bahrain, Brazil and Sweden. It is unloaded from ships to the Material Control yards from where it is supplied to D.R through a series of conveyor system. In D.R, iron oxide is reduced to sponge iron in the vertically mounted shaft furnace using reducing gases such as hydrogen and carbon monoxide. This sponge iron is conveyed to electric arc furnace through different conveyor system. Sponge iron is melted and refined in the Electric Arc Furnaces and then casted into billets form in the Continuous Casting Shops. Billet is also a saleable product which QASCO exports to other countries. The billets are re-heated and rolled through different strands in the Rolling Mills and finally produces the saleable steel bars. QASCOs products are sold in local markets as well as exported to other countries.
D.R. PLANT
D.R. Plant was commissioned in the year 1978 and started commercial production from the month of August 1978. This is a 400 series module, gas based direct reduction plant , based on Midrex technology. The original capacity of the plant was 52 T/Hr. Owing to different debottlenecking process and other modifications, D.R Plant production rate has now increased above 96 T/Hr. The main facilities in the D.R plants are; 1- Reduction Furnace 2- Reformer and Heat Recovery System 3- De-sulphurizing Facility. 4- Oxygen Injection System and Oxide Coating System 5- Main Control Room. The reduction furnace is used for reducing the oxide pellet to sponge iron and reformer for making the reducing gases. Iron oxide is continuously charged into the vertically mounted furnace from the top. In the furnace, the iron oxide undergoes through a series of reduction reactions with hot reducing gases such as hydrogen and carbon monoxide. The reduced pellets are cooled in the lower part of the furnace by a circulating cooling gas system before discharging through the bottom of the furnace. Reducing gases are made in the reformer using natural gas as a feed stock. De-sulfurizing facility is to remove hydrogen sulfide from the natural gas before being introduced into the reformer. Hydrogen sulfide is a poison to the reformer catalyst and will reduce its activity. Oxygen injection system and oxide coating system are plant improvements carried out in the year 2003, to enhance productivity. The plant facilities can be categorically sub-divided in to different systems ( respective code numbers also given ). A B C D E F G H M S Process system Combustion system Flue gas system Seal gas & Purge gas system Process water system Oxide material handling system Instrument & Plant air system Product material handling system Machinery cooling water system Sea water system
D.R.Process
The method of producing sponge iron from iron ore through reduction reactions is known as direct reduction process. There are different types of direct reduction process in the world, such as a) Midrex Process b) Puofer Process c) Hyl Process and d) SL/RN process. QASCO adopted the Midrex Process. Midrex process has two main facilities, one is a reduction furnace and the other is a reformer. The reduction furnace is used for reducing the oxide pellets to sponge iron, and the reformer is used for making reducing gas. The main raw material for direct reduction plant is iron oxide in the form of pellet. Lump ore is also used in some plants because of its low cost in comparison to pellets. Natural Gas is the other raw material used in D.R plant for making reducing gases in the reformer. Natural gas is converted in to carbon monoxide ( CO ) and hydrogen ( H2 ) which is used as the reducing gases. Iron oxide pellets or lump ore are charged into the vertically mounted reduction furnace from the top. It is treated in the reduction zone of the furnace with reducing gases consisting of H2 and CO at a temperature range of 900 ~ 985C.The iron oxide, having the main constituent Hematite ( Fe2O3 ) is reduced to sponge iron after the following chemical reactions; Fe2O3 + 3H2 = 2Fe + 3H2O Fe2O3 + 3CO = 2Fe + 3CO2. The reduced pellet is further subjected to carbon forming reactions, with carbon monoxide and methane. 3Fe + 2CO = Fe3C + CO2 3Fe + CH4 = Fe3C + 2H2 In the lower part of the furnace, the hot sponge iron is cooled by the cooling gas before discharging through the bottom of the furnace. The spent gas from the furnace is again circulated by the process gas compressors through the reformer where it is reformed in to CO and H2 by reacting with hydro- carbons, mainly CH4. The reactions are; CH4 + H2O = CO + 3H2 CH4 + CO2 = 2CO + 2H2 The required temperature for these endothermic, reforming reactions is supplied by 110 main burners and 33 auxiliary burners spread across the reformer. Natural gas is the fuel in the auxiliary burners where as, in the main burners, natural gas plus a portion of return gas from furnace are the fuels .The burnt gas in the reformer is known as flue gas which contains mainly nitrogen, water vapor, carbon dioxide and small amount of oxygen. The heat energy is recuperated from the flue gas partially to heat up the burner air and reformer feed mix gas and finally the flue gas is vented to atmosphere through stacks.
COMBUSTION SYSTEM
Combustion system function is to maintain the reformer to be at the reforming temperature. This system can be classified in to two, 1) Auxiliary combustion system. 2) Main combustion system.
DE-SULPHURIZING SYSTEM
The purpose of this facility is to remove hydrogen sulfide ( H2S ) from the natural gas being used in D.R plant, by the stretford de-sulfurizing process. This plant consists two absorbers, one scrubber, two mist eliminators, one reaction tank, three oxidizers, balance pit, solution pumps, oxidizer blowers and a filter press. De-sulfurizing plant receives natural gas from the gas receiving station , having controlled the gas pressure at around 8.0 kg/cm2. This pressure is further lowered to 5.0 ~ 5.5 kg/cm2 in D.S and the gas is supplied first to a knock out pot where the condensates are removed. Then the gas enters the first absorber through the bottom, comes in contact with the stretford solution which is sprayed from the top of the absorber. The stetford solution absorbs H2S from the gas to as low as 1 PPM from around 3000 PPM. Natural gas comes out from the first absorber from the top, enters the second absorber and goes through the same process. After the second absorber, the gas is getting cleansed with water sprays in a scrubber and then supplied directly for D.R use. The stretford solution after H2S absorption, undergoes re-generation reactions in a reaction tank and three downstream oxidizers before being pumped back to the absorbers. The chemical reaction during this process are as follows;
H2S + Na2Co3 = NaHS + NaHCo3
At first NaVO3 ( Sodium Meta-Vanadate ) reacts with NaHS ( Sodium Hydrogen Sulfide ) and produces elemental sulfur. Reduced sodium metavanadate ( Na2V4O7) is re-oxidized to NaVO3 by Na2ADA. The reduced ADA ( Na2ADA-H2 ) is re-oxidized to Na2ADA by air. Na2CO3 ( Sodium Carbonate ) or NaOH ( Sodium hydroxide ) can be utilized as the alkali for this process.