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PRECIPITATION BY GAS CARBON MONOXIDE

RENDY HARRISTA 3334091122
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OUTLINE
1. 2.

Introduction Reduction Reactions of Metal Ions with Carbon Monoxide in Aqueous Solutions Basic Theory Reduction of Silver Acetate by Carbon Monoxide Reduction of Cupric Salts in Aqueous Solutions by Carbon Monoxide Application References
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3. 4.

5.

6. 7.

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INTRODUCTION
The process of forming PRECIPITATION

a precipitate from a solution

KINDS of PRECIPITATION by Precipitation by gas Hydrogen Precipitation Precipitation Precipitation

GAS

by gas Carbon Monoxide by gas Sulphur Dioxide by gas Hyrogen Sulphate

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Reduction Reactions of Metal Ions with Carbon Monoxide in Aqueous Solutionsof metals have been successfully produced A number

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from aqueous solution when subjected to carbon monoxide. The severity of the conditions necessary for the reactions to proceed at reasonable rates may vary from atmospheric CO pressure and room temperature.

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Basic Theory
The

reduction of a divalent metal ion in aqueous solution by carbon monoxide takes place according to the equation:

M2+ + CO + H2OM + CO2 + 2H+

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CARBON MONOXIDE REDUCTION OF AQUEOUS SILVER ACETATE

Rate

of Carbon Monoxide Reduction of Silver(I) Early experiments demonstrated that at low pH the reduction of AgClO4 solutions was very slow even at temperatures of 175C and CO pressures of 20 atm. When the solutions were buffered with NaOAc and HOAc, however, the rates were readily measured under much milder conditions by the pressure-drop method.

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CONT . . .

The observed kinetics are consistent with the formation of intermediate complexes by the insertion of a carbon monoxide molecule between a silver ion and a co-ordinated oxygen-donating base according to the following mechanism:

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CONT. . .

Chemistry and Stoichiometry of the Reaction When dissolved silver undergoes reduction by carbon The Ag(I)-CO-C02 stoichiometry of reaction was monoxide temperatures by analyzing liquid and in acid solution the reaction examined at several products aretaken after about 50-60 % reaction had gas samples silver metal and carbon dioxide and experimental occurred. Solution composition according to the conditions that gave relatively fast reduction rates were reaction:

selected. The results of these measurements, as summarized in Table, agree within 10% with the stoichiometry represented by reaction
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Effect of Carbon Monoxide Pressure

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Effect of Acetic Acid

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Effect of Temperature

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THE REDUCTION OF CUPRIC SALTS IN AQUEOUS SOLUTIONS BY CARBON MONOXIDE

Rate

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of Carbon Monoxide Reduction of Cu(II)

Recently McAndrew and' Peters began a study of the kinetics of the Cu(II)-CO reduction reaction using the pressure-drop technique. The pressure time curves obtained i n these studies showed pressure minimal and were interpreted as representing two stages - of reduction, the first being from Cu(II) to Cu(I) which follows a stoichiometry consistent with the overall reaction

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CONT . . .
And

a second stage involving either further reduction to metal or hydrolysis to Cu20 according to the reactions

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Effect of Carbon Monoxide Pressure

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Effect of Increaseing Carbon Monoxide Pressure

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APPLICATION
Recovery

of copper, by copper smelters slag at Ghatsila (Bihar) and Khetri (Rajasthan), India.

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REFERENCES
McAndrew,

R.T., and Peters, E., "The Displacement of Silver from Acid Solutionr by Carbon Monoxide", XVIIIth Congress, International Union of Pure and Applied Chemistry, Montreal, 1961. F. 1980. Extractive Metallurgy, volume 2,Gordon and Breach, New York and London. . J . Byerley, and E. Peters, "The Reduction of Cupric Salts i n Aqueous Solutions by Carbon Monoxide", to be published i n Metallurgical Society Conferences, Hydrometallurgy: Proceedings of a Symposium sponsored by the Metallurgical Society of A.I.M.E., Annual Meeting, February 24 - March 1, 19 1963, Dallas, Texas.
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Habashi, J

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