Professional Documents
Culture Documents
BY D.MISHRA
SOURCES OF WATER
1. RIVERS, LAKES AND RESEVOIRS (SURFACE DRAINAGE WATER) 2. UNDERGROUND WATERS (SALLOW WALL, DEEP WELL, SPRINGS) 3. RAIN WATER 4. SEA WATER
DRINKING WATER
COOLING WATER
Treatment of Water
1. Clarification
2. Filtration
3. Softening or Demineralisation
Clarification
Pre- Treatment of water Mixing of chemicals with water Coagulation and flocculation Sedimentation Filtration
Coagulants
1. 2. 3. 4. Aluminium Sulphate, Sodium Aluminate Iron sulphate Poly electrolytes (long chain amides) Poly Aluminium Chloride ( PAC )
Factors affecting coagulation 1. pH ( 5.5 8.0 ) for Al2(SO4)3 2. Temperature (30- 400C ) 3. Time
CLARIFLOCCULATOR
Chlorine Lime Flash Alum Mixer
Clarification Flocculation
Raw water
Water quality at Clarifier outlet Turbidity - <20 NTU Residual Chlorine pH - 5.5 to 8.0 0.2 ppm
Filtration
Filtration is the removal of the solid particles from water by passing it through a filtering medium. Filtration is usually a mechanical process does not remove dissolved solids. Filters used in Water Treatment are mainly of two types.
1. Pressure Filters 2. Gravity filters Pressure filters are in closed, round steel shells and function with the pressure of the incoming water. Gravity filters are in steel, wood or concrete containers that are open at the top and function at atmospheric pressure.
Filter Media
Theoretically any inert granular material can be used for filtration. Quarts sand, Silica sand, anthracite coal, garnet may be used for filtration. Silica sand and anthracite are the types of filter media which are commonly used.
IN
For back washing of the GSF water is passed through filter in reverse direction
OUT
Softening Plant
Brine injection SI - Service Inlet SO - Service Outlet BWI - Backwash In BWO - Backwash Out RO - Rinse Out
Service in
SI
BWI
Drain
SO
OBR - 15000 M3
Softening Plant
Ion Exchange reactions:CaCO3 + 2RNa R2Ca + Na2CO3 MgSO4 + 2RNa R2Mg + Na2SO4 Al2(SO4)3 + RNa CaCl2 + 2RNa Ca(HCO3)2 + 2RNa 2R3Al + 3Na2SO4 R2Ca +2NaCl R2Ca + 2NaHCO3
Softening Plant
Regeneration Reactions :R2Ca + NaCl R2Mg + 2NaCl R3Al + 3NaCl 2RNa + CaCl2 2RNa + MgCl2 3RNa + AlCl3
ION EXCHANGE MATERIAL ARE SYNTHETIC RESIN MADE BY POLYMERISATION OF STYRENE & DIVINYL BENZENE. MAJOR PORTION IS STYRENE (80-92%) & MINOR PORTION IS DIVINYL BENZEND (8-20%). THE DVB ACTS AS A CROSOLINK TO HOLD THE LONG CHAIN.
Ion exchange is reversible inter-change of ions between a solid and liquid in which there is no permanent change in the structure of the solid i.e. ion exchange resin. Ion exchange procedure is used in water softening and deionization. It also provides a method of separation that is useful in many chemical processes like separation of lanthanides. The utility of ion exchange resin rests on its ability to get regenerated so that these can be reused again and again.
PROCESS OF ION EXCHANGE Reversible: Ion exchange is a reversible process therefore, resin can be converted from one ionic form to the other form, number of times and reused. Regeneration: The process of converting resin to the desired ionic form is called regeneration. Exhaustion: The resin is said to be exhausted when it cannot exchange ions without effecting the desired quality of water.
3.Strong base anion resin(SBA): The Strong base anion resins derived their functionality from quaternary ammonium exchange sites.These are capable of exchanging anions like Cl-,HCO3-,Silica. Two type of SBA resins are commercially available and commonly referred as Type-I & Type-II. Type-I site have three methyl groups while in Type-II resins an ethanol group replaces one of the methyl groups. The Type-I resin has higher basicity, greater chemical stability but somewhat less exchange capacity and low regeneration efficiency particularly when the resin is exhausted with monovalent anions i.e. chloride and nitrate. It is effective against organics & silica. The Type-I resins are favoured for the high temperature applications where chemical stability difference is most apparent. The Type-II resin is less stable but having slightly more capacity and regeneration efficiency. In general, a TypeII SBA resin is recommended where silica effluent quality is not as critical and also where a relatively high chloride and/or sulphate content prevails in raw water. After exhaustion SBA resin can be regenerated with 4% NaOH.
4.Weak base anion resin(WBA): Weak anion resins derive their functionality from primary (RNH2),secondary(R-NHR)& tertiary amine (R3N)groups. The weak weak-base anion resins remove free minerals acidity(FMA) such as HCl & H2SO4 but doesnt remove weakly ionized acids such silicic acid and bicarbonates. The main advantage of weak base exchangers is that they can be regenerated with stoichiometric amount of regenerant, and are therefore, much more efficient. These have a higher capacity for the removal of chlorides, sulphates. These are used in conjunction with SBA in demineralization system to reduce regenerant cost and to attract organics thereby protecting the more susceptible strongly basic resins, and for service in which carbon dioxide and silica are not important. Where silica removal is not critical, WBA may be used by themselves in conjunction with air stripper to remove CO2(degaser).
Classification of Ion Exchange Resins Based on Functionality Resin Type Strong Acid functional Group sulphonic Configuration R-SO3H Example (INDION) 225
Weak Acid
Carboxylic
R-CH2CHCH3 COOH
CH3 R-CH2N+CH3OHCH3 CH3 R-CH2N+CH3OHCH2 CH2 OH CH3 R-CH2N+HOH- 850 CH3
236
Quaternary Ammonia
FFIP
Quaternary Ammonia
NIP
Tertiary
DM PLANT
From filter water pumps
For circuit rinse
ACF
WAC
SAC
WBA
SBA
MB
Air DEGASSER
To main plant for boiler make up
DM PLANT
Water quality at different stages of Demineralisation process:Feed water to DM plant Turbidity - <2 NTU ACF out Residual chlorine - Nil Turbidity - < 0.5 NTU Cation Exchanger out Na - <2 ppm Degasser out Dissolved CO - <5 ppm
DM Plant
Anion Exchanger out Silica - < 200 ppb Conductivity - < 10 ms/cm pH - 6.8 - 7.2 Mixed bed out Silica - < 20 ppb Conductivity - < 0.1 ms/cm pH - 6.8 - 7.2
BO
Drain
Weak
Strong
NF - Nozzle flushing
Air Vent
SI DF
NF
Air Vent
BI
BO RO SO
SI
BI
Acid/Alkali injection
Drain
BO RO Drain
SO
MIXED BED
Service and Regeneration
Alkali injection
SI NF
Air
Air Vent
Drain
Acid injection
SO
Mixed Bed
Resin Separation
Ion-exchange Reactions
Cation Exchanger During Service NaCl RH + CaCO3 MgSO4 Na2SiO3 During Regenration RNa R2Ca + HCl R2Mg
RNa + HCl R2Ca + H2CO3 R2Mg + H2SO4 RNa +H2SiO3 NaCl RH + CaCl2 MgCl2
Ion-exchange Reactions
Anion Exchanger During Service
HCl ROH + H2CO3 H2SO4 H2SiO3 During Regenration RCl R2CO3 + NaOH R2SO4 R2SiO3 RCl R2CO3 R2SO4 R2SiO3 + + + + H2O H2O H2O H2O
ROH +